Investigating the Impact of Packing and Environmental Factors on the Luminescence of Pt(N^N^N) Chromophores.

Four Pt(II)(N^N^N) compounds featuring DMSO coordination at the fourth position were synthesized. Ligands varied in terms of pyridyl central ring (hydrogen/chlorine substituent) and lateral rings (triazoles with CF substitution or tetrazoles). Coordination to pyridine yielded tetra-nitrogen coordinated Pt(II) complexes or Pt-functionalized polymers using commercial 4-pyridyl polyvinyl (PV) or dimethylaminopyridine. Luminescence behaviors exhibited remarkable environmental dependence. While some of the molecular compounds (tetrazole derivatives) in solid state displayed quenched luminescence, all the polymers exhibited MMLCT emission around 600 nm. Conversely, monomer emission was evident on poly(methyl methacrylate) or polystyrene matrices. DFT calculations were used to analyze the aggregation of the complexes both at the molecular level and coordinated to the PV polymer and their influence on the HOMO-LUMO gaps.