The study concerned technical feasibility, economic profitability, and carbon footprint (CF) analysis of semi-continuous anaerobic digestion (sAD) of organic fraction of municipal solid waste (OFMSW). The research assessed the pre-treatment effect on sAD by varying organic loading rates (OLR) from 3.38 to 6.75 kgvs/md. Three sAD configurations were investigated: hydrodynamic-cavitated (HC-OFMSW), enzymatically pre-treated (EN-OFMSW), and non-pre-treated (AD-OFMSW). Principal Component Analysis and Supervised Kohonen's Self-Organizing Maps combined the experimental, economic, and environmental evaluations. The sAD configurations were grouped predominantly according to the OLR however, within each OLR group the configurations were clustered according to the pre-treatments. The finding highlighted that pre-treatments offset inhibition in sAD of OFMSW due to the OLR increase, being economically profitable and CF negative up to 4.50 kgvs/md for EN-OFMSW and to 5.40 kgvs/md for HC-OFMSW. Whereas sAD-OFMSW remained economically and environmentally viable only up to 3.87 kgvs/md. HC-OFMSW reached the highest performance. In detail, for HC-OFMSW the NPV and CF ranged from 17679.30 to 43827.12 euros and from -51.08 to -407.210 kg COeq/1 MWh daily produced, by decreasing the OLR from 5.40 to 3.87 kgvs/md. These results are fundamental since pre-treatment is usually expensive due to additional energy or chemical requirements.
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http://dx.doi.org/10.1016/j.envpol.2024.123417 | DOI Listing |
Drug Deliv Transl Res
January 2025
Model System for Infection and Immunity, Helmholtz Centre for Infection Research, Inhoffenstr. 7, 38124, Braunschweig, Germany.
Two features of macrophages make them attractive for targeted transport of drugs: they efficiently take up a broad spectrum of nanoparticles (NPs) and, by sensing cytokine gradients, they are attracted to the sites of infection and inflammation. To expand the potential of macrophages as drug carriers, we investigated whether macrophages could be simultaneously coloaded with different types of nanoparticles, thus equipping individual cells with different functionalities. We used superparamagnetic iron oxide NPs (SPIONs), which produce apoptosis-inducing hyperthermia when exposed to an alternating magnetic field (AMF), and co-loaded them on macrophages together with drug-containing NPs (inorganic-organic nanoparticles (IOH-NPs) or mesoporous silica NPs (MSNs)).
View Article and Find Full Text PDFRSC Adv
January 2025
College of Environment and Chemical Engineering, Dalian University Dalian 116622 Liaoning P. R. China
Photocatalytic technology for removing organic dye pollutants has gained considerable attention because of its ability to harness abundant solar energy without requiring additional chemical reagents. In this context, YF spheres doped with Yb, Er, Tm (YF) are synthesized using a hydrothermal method and are subsequently coated with a layer of graphitic carbon nitride (g-CN) with Au nanoparticles (NPs) adsorbed onto the surface to create a core-shell structure, designated as YF: Yb, Er, Tm@CN-Au (abbreviated as YF@CN-Au). The core-shell composites demonstrate remarkable stability, broadband absorption, and exceptional photocatalytic activity across the ultraviolet (UV) to near-infrared (NIR) spectral range.
View Article and Find Full Text PDFFood Chem X
January 2025
Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95060, USA.
Total antioxidant capacity (TAC) is an important indicator for assessing the merit of natural plants and foods. Herein, a visual TAC assay is developed based on the oxidase-like activity of nitrogen-doped carbon nanotubes loaded with Fe nanoparticles (FeNPs@NCNT), which is prepared via high-temperature pyrolysis of metal-organic framework precursors and can catalyze the oxidation of colorless -phenylenediamine (OPD) to colored 2,3-diaminophenazine (DAP). The addition of antioxidants (e.
View Article and Find Full Text PDFSmall
January 2025
Faculty of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji, 721013, China.
Dielectric nanocomposites have garnered significant interest owing to their potential applications in energy storage. However, achieving high energy density (U) and charge/discharge efficiency (η) remains a challenge in their fabrication. In this paper, core-shell structured BaTiO@Polyvinylpyrrolidone (BT@PVP) nanoparticles are prepared, and incorporated into a semi-crystalline polyvinylidene fluoride (PVDF) matrix.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
School of Physics and Electronic Information Engineering, Henan Polytechnic University, Jiaozuo, 454003, China. Electronic address:
Background: Trimethylamine (TMA) is a colorless, volatile gas with a strong irritating odor. Prolonged exposure to a certain amount of TMA can cause symptoms such as dizziness, nausea and difficulty breathing, and may even be life-threatening. Therefore, effective detection of TMA is crucial.
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