A novel method for production of nitrogen fertilizer with low energy consumption by efficiently adsorbing and separating waste ammonia.

Recovering waste NH to be used as a source of nitrogen fertilizer or liquid fuel has recently attracted much attention. Current methods mainly utilize activated carbon or metal-organic frameworks to capture NH, but are limited due to low NH adsorption capacity and high cost, respectively. In this study, novel porous materials that are low cost and easy to synthesize were prepared as NH adsorbents by precipitation polymerization with acid optimization. The results showed that adsorption sites (‒COOH, -OH, and lactone) which form chemical adsorption or hydrogen bonds with NH were successfully regulated by response surface methods. Correspondingly, the dynamic NH adsorption capacity increased from 5.45 mg g to 129 mg g, which is higher than most known activated carbon and metal-organic frameworks. Separation performance tests showed that NH could also be separated from CO and CH. The findings in this study will advance the industrialization of NH polymer adsorbents and provide technical support for the recycling of waste NH.