Dynamics of a silicone oil drop submerged in a stratified ethanol-water bath.

We analyze numerically the Marangoni flow around an immiscible droplet submerged in a stably stratified mixture of ethanol and water. The linear stability analysis shows that the base flow undergoes a supercritical Hopf bifurcation that leads to oscillations. The theoretical prediction for the critical droplet radius is consistent with previous experimental results. Ethanol diffusion in water is critical in the flow stability for both low and high droplet viscosity. Direct numerical simulations of the nonlinear oscillatory flow show that the frequency of those oscillations approximately equals that of the critical eigenmode. The nonlinear convective term of the ethanol diffusive-convective transport equation fixes the amplitude of the droplet oscillations. The viscous dissipation associated with the Marangoni flow inside the droplet considerably reduces the oscillation.