Comparative study of electro-Fenton and photoelectro-Fenton processes using a novel photocatalytic fuel cell electro-Fenton system with g-C N @N-TiO and Ag/CNT@CF as electrodes.

In this study, a novel photocatalytic fuel cell electro-Fenton (PFC-EF) system was constructed using g-C N @N-TNA and Ag/CNT@CF as electrodes. The composition, structure, and morphology of the electrodes were obtained. The g-C N @N-TNA, with its 2.37 eV band gap and 100 mV photovoltage, has excellent excitation properties for sunlight. Ag/CNT@CF with abundant pores, CNT 3D nanostructures, and Ag crystals on the surface can improve the electro-Fenton efficiency. A comparative study of rhodamine B (RhB) degradation was performed in this system. It has been shown that electric fields can greatly enhance the oxidation efficiency of both anode photocatalysis and the cathode electro-Fenton process. Under optimal conditions, RhB can be completely removed by the photoelectro-Fenton (PEF) process. The energy consumption of the PEF system was obtained. The electrical energy per order (EE/O) is only 9.2 kWh/m ·order, which is only 16.5% of EF and 2.2% of PFC-EF system. The mineralization current efficiency (MCE) of the PEF system reached 93.3% for a 2-h reaction. Therefore, the PEF system has the advantage of saving energy. The kinetic analysis shows that the RhB removal follows a first-order kinetic law, and the reaction rate constant reaches 0.1304 min , which is approximately 5.2 times larger and 4.0 times larger than the electro-Fenton and PFC-EF processes, respectively. RhB removal is a coupling multimechanism in which an electric field enhances photoelectron migration, Ag loading improves H O generation, UV light coupled with H O promotes hydroxyl radical (٠OH) generation, and the nanoconfinement effect of CNTs promotes ٠OH accumulation in favor of RhB degradation. PRACTITIONER POINTS: Novel efficiency photocatalytic fuel cell electro-Fenton system was constructed. The electric field greatly enhances the photocatalytic fuel cell electro-Fenton system. Multiple coupling mechanisms of UV/H2O2, UV/Fenton and photo-electro-Fenton have been revealed.