AI Article Synopsis
- * A new compound called diacetylene-functionalized cyanostilbene luminogen (DACSM) is created by linking diacetylene and cyanostilbene to generate multiple molecular states using only one dye.
- * The DACSM exhibits tunable properties through thermal and photochemical reactions, leading to applications like switchable optical patterns and secure coding methods.
Article Abstract
To develop advanced optical systems, many scientists have endeavored to create smart optical materials which can tune their photophysical properties by changing molecular states. However, optical multi-states are obtained usually by mixing many dyes or stacking multi-layered structures. Here, multiple molecular states are tried to be generated with a single dye. In order to achieve the goal, a diacetylene-functionalized cyanostilbene luminogen (DACSM) is newly synthesized by covalently connecting diacetylene and cyanostilbene molecular functions. Photochemical reaction of cyanostilbene and topochemical polymerization of diacetylene can change the molecular state of DACSM. By thermal stimulations and the photochemical reaction, the conformation of polymerized DACSM is further tuned. The synergetic molecular cooperation of cyanostilbene and diacetylene generates multiple molecular states of DACSM. Utilizing the optical multi-states achieved from the newly developed DACSM, switchable optical patterns and smart secret codes are successfully demonstrated.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10953535 | PMC |
| http://dx.doi.org/10.1002/advs.202307791 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Lateral heterostructures of WS and MoS monolayers for photo-synaptic transistor.
Sci Rep
March 2024
Strategic Technology Research Institute, Korea Research Institute of Standards and Science, Daejeon, 34113, Republic of Korea.
Von Neumann architecture-based computing, while widely successful in personal computers and embedded systems, faces inherent challenges including the von Neumann bottleneck, particularly amidst the ongoing surge of data-intensive tasks. Neuromorphic computing, designed to integrate arithmetic, logic, and memory operations, has emerged as a promising solution for improving energy efficiency and performance. This approach requires the construction of an artificial synaptic device that can simultaneously perform signal processing, learning, and memory operations.
View Article and Find Full Text PDFPhotochemically and Thermally Programmed Optical Multi-States from a Single Diacetylene-Functionalized Cyanostilbene Luminogen.
Adv Sci (Weinh)
March 2024
Department of Polymer-Nano Science and Technology, Department of Nano Convergence Engineering, Jeonbuk National University, Jeonju, 54896, Republic of Korea.
Article Synopsis
- * A new compound called diacetylene-functionalized cyanostilbene luminogen (DACSM) is created by linking diacetylene and cyanostilbene to generate multiple molecular states using only one dye.
- * The DACSM exhibits tunable properties through thermal and photochemical reactions, leading to applications like switchable optical patterns and secure coding methods.
An Optoelectronic Synapse Based on Two-Dimensional Violet Phosphorus Heterostructure.
Adv Sci (Weinh)
August 2023
Shanghai Key Lab for Future Computing Hardware and System, School of Microelectronics, Fudan University, Shanghai, 200433, China.
Neuromorphic computing can efficiently handle data-intensive tasks and address the redundant interaction required by von Neumann architectures. Synaptic devices are essential components for neuromorphic computation. 2D phosphorene, such as violet phosphorene, show great potential in optoelectronics due to their strong light-matter interactions, while current research is mainly focused on synthesis and characterization, its application in photoelectric devices is vacant.
View Article and Find Full Text PDFRoom Temperature Phosphorescence Emission From Multi-States.
Front Chem
February 2022
Guangxi Key Laboratory of Optical and Electronic Materials and Devices, College of Materials Science and Engineering, Guilin University of Technology, Guilin, China.
Article Synopsis
- Organic room temperature phosphorescence (RTP) materials are gaining interest for their unique properties, particularly organic luminogens that emit RTP in solid forms.
- In this study, two fluorene derivatives were discovered to exhibit RTP emission in degassed organic solvents, polymer-doped films, and crystalline states, showing versatility.
- These luminogens emitted different colors and had varying phosphorescence lifetimes across multiple states, marking a significant advance as it's the first report on diverse organic RTP in solution as well.
Graphene-ferroelectric metadevices for nonvolatile memory and reconfigurable logic-gate operations.
Nat Commun
January 2016
Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology(KAIST), Daejeon 305-701, Republic of Korea.
Memory metamaterials are artificial media that sustain transformed electromagnetic properties without persistent external stimuli. Previous memory metamaterials were realized with phase-change materials, such as vanadium dioxide or chalcogenide glasses, which exhibit memory behaviour with respect to electrically/optically induced thermal stimuli. However, they require a thermally isolated environment for longer retention or strong optical pump for phase-change.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!