Assessing the shooting distance of lead-free ammunition regardless of composition using Laser Induced Breakdown Spectroscopy.

Unlabelled: At present, it is challenging to accurately determine firearm shooting distances in the case that lead-free ammunition is involved, largely because different manufacturers use different primer compositions. Laser-induced breakdown spectroscopy (LIBS) allows the simultaneous detection of multiple elements with high sensitivity and so may represent a solution to this problem. Previous studies have, in fact, demonstrated that LIBS can be used to determine shooting distances when working with gunshot residues from conventional ammunition based on scanning fabric surfaces. The present study confirms that the shooting distance can be ascertained using LIBS to detect copper originating from the ammunition casing and projectile but not the primer on fabric surfaces. This estimation can be performed regardless of the primer composition of lead-free ammunition.

Key Points: Evaluation of gunshot residue from lead-free ammunition using scanning electron microscopy-energy dispersive X-ray analysis indicated that 40% of the particles contained copper.The iForenLIBS system allowed the detection of copper-containing particles on fabric surfaces after firing at different distances with high sensitivity.Laser-induced breakdown spectroscopy can determine the shooting distance of lead-free ammunition through copper detection even in ammunition that does not used this element in the primer.This technique can generate density maps allowing the evaluation of short, medium, and long-range shooting distances.