Flood irrigation increases the release of phosphorus from aquifer sediments into groundwater.

Nonpoint source pollution caused by agricultural activities has long attracted widespread attention from people in society and academia. Many studies have found that human activities not only convey exogenous pollutants into aquifers but also affect the mobilization and transport of geogenic pollutants in aquifers. Geogenic groundwater with high phosphorus concentrations has been found, but it is unclear whether the changes in hydrogeochemical conditions caused by flood irrigation in paddy fields affect the fate of phosphorus. We investigated the temporal and spatial distribution characteristics of phosphorus in groundwater under the influence of flood irrigation through laboratory experiments, proved its impact on phosphorus in groundwater, and explored the mechanisms influencing P concentrations. The results show that flood irrigation can increase the release of phosphorus in the aquifer media and greatly increase the phosphorus concentration in the groundwater of the study area, which has a negative impact on groundwater quality. The main mechanism of increase in phosphorus concentration in groundwater involves an increase in the reducibility of the aquifer via flood irrigation; as a result, iron oxides are reductively dissolved and iron-bound phosphorus is released into the groundwater. Changes in pH also result in the dissolution of calcium phosphate minerals and the release calcium-bound phosphorus. This study not only advances the theory of multielement-coupled hydrogeochemistry but also provides a reference for agricultural planning and groundwater pollution prevention and control in rice-growing areas.