Systematic Photoassisted Access to Designer Polyheterocycles via Modular Blocks and Scaffolding.

Org Lett

Department of Chemistry and Biochemistry, University of Denver, Denver, Colorado 80208, United States.

Published: January 2024

AI Article Synopsis

  • - The study focuses on creating diverse polyheterocycles using a method that involves light-assisted chemical reactions.
  • - It utilizes a specific process called decarboxylative aromatization, which transforms initial products from intramolecular cycloadditions of azaxylylenes.
  • - These azaxylylenes are combined with heteroaromatic compounds that have unsaturated parts to form the desired complex structures.

Article Abstract

Diverse polyheterocycles are accessed via scaffolded photoassisted synthesis involving decarboxylative aromatization of the primary photoproducts from intramolecular cycloadditions of azaxylylenes and tethered heteroaromatic unsaturated pendants.

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Source
http://dx.doi.org/10.1021/acs.orglett.3c04186DOI Listing

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