In this study, for the first time, Schreb. (E, hoary willowherb) aqueous extract was introduced into edible biopolymer films and its influence on physicochemical properties of the final products were investigated. Potato starch was gelatinized in the herbal tea to obtain thermoplastic starch (TPS) films via the casting method. The characterization of the films included mechanical, antioxidative, water (WVTR, contact angle, swelling degree) and UV radiation barrier properties as well as microstructure analysis (SEM). Obtained results indicated that the presence of the extract (rich in phenolic compounds) in the films acted as a co-plasticizer for starch and led to a higher elongation at break, up to 70%, with a parallel increase in tensile strength up to ca. 9 MPa. Moreover, TPS films with E exhibited lower WVTR values and absorption of UV light in comparison with the control TPS film. DPPH scavenging activity of TPS E films immersed in methanol was ca. 92%, and it was related to the release of the extract into liquid media. Novel TPS E films are characterized by multifunctional properties that can be used, e.g., in the active packaging sector.
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http://dx.doi.org/10.3390/polym16010064 | DOI Listing |
Antioxidants (Basel)
December 2024
Department of Polymer Engineering, Institute for Polymers and Composites (IPC), University of Minho, 4804-533 Guimarães, Portugal.
The packaging industry has made efforts to reduce food waste and improve the resilience of food systems worldwide. Active food packaging, which incorporates active agents, represents a dynamic area where industry and academia have developed new strategies to produce innovative and sustainable packaging solutions that are more compatible with conventional options. Due to health and environmental concerns, industries have sought alternatives to petroleum-based materials and have found biopolymers to be a viable option because of their biodegradable and safe nature.
View Article and Find Full Text PDFPolymers (Basel)
November 2024
Department of Packaging and Materials Technology, Faculty of Agro-Industry, Kasetsart University, 50 Ngam Wong Wan Rd., Latyao, Chatuchak, Bangkok 10900, Thailand.
The development of biodegradable active packaging is a relevant topic demanding the development of film properties, biodegradability, and the potential to preserve food quality. This study aimed to develop thermoplastic starch (TPS) blended with polybutylene adipate-co-terephthalate (PBAT) films via blown-film extrusion containing ascorbyl palmitate (AP) and sodium ascorbyl phosphate (SAP) as antioxidants. The morphology, mechanism, and barrier and antioxidant properties of the films were analyzed to determine the presence of AP, SAP, and their interaction effect on the film properties.
View Article and Find Full Text PDFJ Contemp Brachytherapy
August 2024
Department of Radiation Oncology, University of Utah, Salt Lake City, Utah, USA.
J Appl Clin Med Phys
November 2024
Department of Medical Physics, Shanghai Proton and Heavy Ion Center, Shanghai Key Laboratory of Radiation Oncology, Shanghai Engineering Research Center of Proton and Heavy Ion Radiation Therapy, Shanghai, China.
Purpose: To commission the RayStation (RS) TPS (treatment planning system) for scanned CIRT (carbon-ion radiotherapy) utilizing pencil beam algorithms (PBv4.2).
Methods: The beam model commissioning entailed employing 1D single beams and 2D monoenergetic fields to validate spot profiles with films, assess beam range using Peakfinder measurements, and evaluate fragment spectra through dose-averaged linear energy transfer (LETd) calculations.
Int J Biol Macromol
December 2024
Department of Packaging and Materials Technology, Faculty of Agro-Industry, Kasetsart University, 50 Ngam Wong Wan Rd., Latyao, Chatuchak, Bangkok 10900, Thailand; Center for Advanced Studies for Agriculture and Food, Kasetsart University, 50 Ngam Wong Wan Rd., Latyao, Chatuchak, Bangkok 10900, Thailand. Electronic address:
Phosphate derivatives contain a high number of reactive groups that interact functionally with various polymers. Tetrasodium pyrophosphate (Na₄P₂O₇), sodium tripolyphosphate (Na₅P₃O₁₀), and sodium hexametaphosphate (Na₆(PO₃)₆) were incorporated into bioplastic polybutylene-adipate-terephthalate (PBAT) blended with thermoplastic cassava starch (TPS) in blown films. Their physicochemical, morphological, thermal, and antimicrobial properties were investigated.
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