Modulation of Δ and room temperature phosphorescence in carbazole derivatives.

Chem Commun (Camb)

School of Chemical Sciences, UM DAE Centre for Excellence in Basic Sciences, University of Mumbai, Kalina, Santacruz (E), Mumbai 400098, India.

Published: February 2024

A simple strategy to modulate the singlet-triplet energy gap in 3,6-diaryl--acetophenylcarbazole derivatives is developed. Different substituents significantly influenced Δ, which is correlated for the first time with the singlet-triplet state dipole moments. Phosphorescence at ambient conditions in powder form ( is up to 248 μs) and ultra long lifetime (up to 2.2 s) at 77 K is observed.

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Source
http://dx.doi.org/10.1039/d3cc05119fDOI Listing

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