Novel imidazole-containing boronic acid and palladium hybrid catalysis for regioselective -allylation of carbohydrates has been developed. This catalytic process enables the introduction of a useful allyl functional group into the equatorial hydroxy group of -1,2-diols of various carbohydrates with low catalyst loading and excellent regioselectivities. This is the first report on hybrid catalysis in combination with a Lewis base-containing boronic acid and a transition metal complex.
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| http://dx.doi.org/10.1021/acs.joc.3c02445 | DOI Listing |
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