Fullerene-like Niobovanadate Cage Built from {(Nb)V } Pentagon.

The striking aesthetic appeal of fullerene-like clusters has captured the interest of researchers. Nevertheless, the assembly of fullerene-like polyoxovadanadate (POV) cages remains a significant challenge due to the scarcity of suitable pentagonal motif. Herein, we have successfully synthesized the first fullerene-like all-inorganic POV cage, {(V O)V Nb O (H O) } (V Nb ), by introducing Nb into the POVs. V Nb is assembled by 12 heterometallic {(Nb)V } pentagons through sharing V centers with I symmetry, reminiscent of C . To our knowledge, the fullerene-like V Nb not only represents the highest-nuclearity POV cage but also stands as the first niobovanadate cluster. Notably, V Nb exhibits excellent solution stability, as confirmed by ESI-MS, FT-IR and UV/Vis spectra. As there is no protection organic ligand on its outer surface, V Nb can be further modified with Cu-complexes to form a fullerene-like cluster based zigzag chain (Cu-V Nb ).