Optimization of KCO exposure conditions using response surface methodology for CO capture with 2-methylpiperazine and monoethanolamine as promoters.

In this study, the optimization of potassium carbonate (KCO) exposure conditions for CO capture with the use of 2-methypiperazine (2MPz) and monoethanolamine (MEA) as promoters was investigated. The tested operating conditions for the CO capture process included the pH, temperature, KCO dose, gas flow rate, and pressure, and their effect on the CO absorption/desorption rate and CO absorption efficiency was assessed. Response surface methodology (RSM) was also employed to determine the equations for the optimal long-term operating conditions. The results showed that the CO absorption rate and efficiency increased under KCO exposure with an increase in the pressure and loading rate. Moreover, for the temperature the absorption efficiency first increase and then decreases with increase in temperature, however, the with increase in temperature the faster absorption were observed with lower absorption loading rate. Furthermore, pH had a more complex effect due to its variable effects on the speciation of bicarbonate ions (HCO) and carbonate ions (CO). Under higher pH conditions, there was an increase in the concentration of HCO, which has a higher CO loading capacity than CO. Contouring maps were also used to visualize the effect of different exposure conditions on the CO absorption rate and efficiency and the role of 2MPz and MEA as promoters in the KCO solution for CO absorption. The results showed that the mean CO absorption rate was 6.76 × 10 M/L/s with an R of 0.9693 for the KCO solution containing 2MPz. The highest absorption rate (6.56-7.20 × 10 M/L/s) was observed at a temperature of 298-313 K, a pressure of >2 bar, a pH of 8-9, and a loading rate of 80-120 L/h for a concentration of 1-3 M KCO and 0.05-1.5 M 2MPz. The CO absorption efficiency exhibited a variation of 56-70% under the same conditions.