Multicomponent excited states endow copper iodide clusters with allochroic properties under diverse stimuli. However, crystal states are required, and cluster stimulus sensitivity hampers electroluminochromism. We developed PhQPCuX (X = Cl, Br, and I) with the first μ-bridging tetraphosphine ligand, whose CuX crowns were exposed to external stimulus. The increased proportion of CuX results in equal contributions of cluster- and ligand-centered components to excited states, the former of which is highly sensitive to grind, vapor, and, especially, electric stimuli, due to semi-exposed CuX. Through vacuum evaporation and vapor fumigation of cluster-based emissive layers, the diodes' electroluminescence colors changed from yellow to white. Joule heat during device operation induced further color variation to orange, corresponding to Commission Internationale de l'Eclairage coordinates of PhQPCuI changed from (0.44 ± 0.1, 0.34 ± 0.1) to (0.57 ± 0.1, 0.42 ± 0.1). These results demonstrate the superiority of luminescent clusters in accurate excited-state modulation, holding promise for wide applications.
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