Three- . two-carbon N-to-N connectors give rise to monomeric, tetrahedral NSCo(II) ( = 4.24 BM) or dimeric [(NS)Co(II)] (diamagnetic) complexes, respectively. Differences in the derivative products of the Lewis acid receivers, W(CO) and W(CO), illustrate nucleophilicity of the thiolate sulfur lone pairs in each case, as well as their structural control.
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