In recent years, mid-infrared parametric upconversion imaging, a nonlinear optical method that involves converting mid-infrared light into visible images, has significantly advanced and has shown considerable potential for various applications, including biomedical imaging and remote sensing. While diffraction-based parametric upconversion imaging modeling in standard thin birefringence crystals have been addressed, the numerical framework developed so far fails to address long aperiodic poled crystals. Specifically, diffraction-based analysis of the recent broadband adiabatic frequency upconversion imaging, which allows simultaneous image upconversion of extremely broadband signals is still lacking. Here, we introduce a diffraction-based numerical simulation framework for predicting the evolution of the nonlinear image/signal generation in upconversion imaging systems. This generalized framework can handle both periodically and aperiodically poled crystal designs. Specifically, the model captures faithfully and addresses the varying image magnification arising from upconversion at a Fourier plane of a multiwavelength object. The numerical simulations are validated by experimental measurements of broadband upconversion 3-5 µm mid-IR images to the visible-NIR, showing a good agreement. Moreover, the model allows the exploration of the trade-offs in the spectral span when moving to the full visible range. Our numerical framework will be useful for the interpretation of experimental results obtained in an imaging setting with nonlinear optical elements.
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http://dx.doi.org/10.1364/OE.498767 | DOI Listing |
Nanoscale Horiz
January 2025
Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.
Upconverting nanoparticles (UCNPs) convert near-infrared (IR) light into higher-energy visible light, allowing them to be used in applications such as biological imaging, nano-thermometry, and photodetection. It is well known that the upconversion luminescent efficiency of UCNPs can be enhanced by using a host material with low phonon energies, but the use of low-vibrational-energy inorganic ligands and non-epitaxial shells has been relatively underexplored. Here, we investigate the functionalization of lanthanide-doped NaYF UCNPs with low-vibrational-energy SnS ligands.
View Article and Find Full Text PDFAgeing Res Rev
January 2025
Department of Pharmaceutics, NIMS Institute of Pharmacy, NIMS University, Jaipur 303121, Rajasthan, India.
Neurodegenerative diseases (NDs) are debilitating disorders characterized by the progressive and selective loss of function or structure in the brain and spinal cord. Both chronic and acute forms of these diseases are associated with significant morbidity and mortality, as they involve the degeneration of neurons in various brain regions. Misfolding and aggregation of amyloid proteins into oligomer and β-sheet rich fibrils share as common hallmark and lead to neurotoxicity.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Institute of Optoelectronic Technology, Fuzhou University, Fuzhou 350116, China.
Colloidal quantum dot (CQD) near-infrared (NIR) upconversion devices (UCDs) can directly convert low-energy NIR light into higher energy visible light without the need for additional integrated circuits, which is advantageous for NIR sensing and imaging. However, the state-of-the-art CQD NIR upconverters still face challenges, including high turn-on voltage (), low photon-to-photon (p-p) upconversion efficiency, and low current on/off ratio, primarily due to inherent limitations in the device structure and operating mechanisms. In this work, we developed a CQD NIR UCD based on a hole-only injection mechanism.
View Article and Find Full Text PDFNanoscale
January 2025
McMaster University, Department of Engineering Physics, Hamilton, ON M8S 4K1, Canada.
Nano Lett
January 2025
Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012, China.
Lanthanide-doped fluoride nanocrystals have emerged as promising tools in biomedicine, yet their applications are still limited by their low luminescence efficiency. Herein, we developed highly efficient lithium-based core-shell-shell (CSS) nanoprobes (NPs) featuring a rhombic active domain and a spherical inert protective shell. By introducing Yb as an energy transfer bridge and optimizing the CSS design, a remarkable 1643-fold enhancement in visible emission and a 33-fold increase in NIR emission are achieved compared to original nanoparticles.
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