The thermal Hall effect in magnetic insulators has been considered a powerful method for examining the topological nature of charge-neutral quasiparticles such as magnons. Yet, unlike the kagome system, the triangular lattice has received less attention for studying the thermal Hall effect because the scalar spin chirality cancels out between adjacent triangles. However, such cancellation cannot be perfect if the triangular lattice is distorted. Here, we report that the trimerized triangular lattice of multiferroic hexagonal manganite YMnO produces a highly unusual thermal Hall effect under an applied magnetic field. Our theoretical calculations demonstrate that the thermal Hall conductivity is related to the splitting of the otherwise degenerate two chiralities of its 120˚ magnetic structure. Our result is one of the most unusual cases of topological physics due to this broken Z symmetry of the chirality in the supposedly paramagnetic state of YMnO, due to strong topological spin fluctuations with the additional intricacy of a Dzyaloshinskii-Moriya interaction.
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http://dx.doi.org/10.1038/s41467-023-44448-9 | DOI Listing |
Sci Rep
December 2024
Department of Physics, University of Liverpool, Oxford Street, Liverpool, L69 7ZE, UK.
Topological semimetals have recently garnered widespread interest in the quantum materials research community due to their symmetry-protected surface states with dissipationless transport which have potential applications in next-generation low-power electronic devices. One such material, [Formula: see text], exhibits Dirac nodal arcs and although the topological properties of single crystals have been investigated, there have been no reports in crystalline thin film geometry. We examined the growth of [Formula: see text] heterostructures on a range of single crystals by optimizing the electron beam evaporation of Pt and Sn and studied the effect of vacuum thermal annealing on phase and crystallinity.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St. Andrews, KY16 9ST, U.K.
The [1,2]-rearrangement of allylic ammonium ylides is traditionally observed as a competitive minor pathway alongside the thermally allowed [2,3]-sigmatropic rearrangement. Concerted [1,2]-rearrangements are formally forbidden, with these processes believed to proceed through homolytic C-N bond fission of the ylide, followed by radical-radical recombination. The challenges associated with developing a catalytic enantioselective [1,2]-rearrangement of allylic ammonium ylides therefore lie in biasing the reaction pathway to favor the [1,2]-reaction product, alongside controlling a stereoselective radical-radical recombination event.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455, USA.
The crystallographic restriction theorem constrains two-dimensional nematicity to display either Ising (Z_{2}) or three-state-Potts (Z_{3}) critical behaviors, both of which are dominated by amplitude fluctuations. Here, we use group theory and microscopic modeling to show that this constraint is circumvented in a 30°-twisted hexagonal bilayer due to its emergent quasicrystalline symmetries. We find a critical phase dominated by phase fluctuations of a Z_{6} nematic order parameter and bounded by two Berezinskii-Kosterlitz-Thouless (BKT) transitions, which displays only quasi-long-range nematic order.
View Article and Find Full Text PDFNanoscale Horiz
December 2024
Electrical and Computer Engineering, The Grainger College of Engineering, University of Illinois Urbana-Champaign, Urbana, USA.
Antiferromagnetic materials have several unique properties, such as a vanishingly small net magnetization, which generates weak dipolar fields and makes them robust against perturbation from external magnetic fields and rapid magnetization dynamics, as dictated by the geometric mean of their exchange and anisotropy energies. However, experimental and theoretical techniques to detect and manipulate the antiferromagnetic order in a fully electrical manner must be developed to enable advanced spintronic devices with antiferromagnets as their active spin-dependent elements. Among the various antiferromagnetic materials, conducting antiferromagnets offer high electrical and thermal conductivities and strong electron-spin-phonon interactions.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
School for Engineering of Matter, Transport, and Energy, Arizona State University, Tempe, AZ 85287, USA.
Thermo-mechanically stabilized nanocrystalline (NC) alloys are increasingly valued for their enhanced mechanical strength and high-temperature stability, achieved through thermodynamic and kinetic stabilization methods. However, their fine-grained structure also increases susceptibility to internal oxidation due to higher atomic diffusivity associated with a greater volume fraction of grain boundaries (GBs). By incorporating solutes that form protective oxides, or the so-called thermally growing oxides (TGO), this vulnerability can be mitigated.
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