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Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes. | LitMetric
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Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes.

Daniel Himmelbauer Fabian Müller Clara Schweinzer Fernando Casas Bruno Pribanic Grégoire Le Corre Debora Thöny Monica Trincado Hansjörg Grützmacher

Chem Commun (Camb)

Department of Chemistry and Applied Biosciences, ETH Zurich Vladimir-Prelog-Weg 1, Zurich CH-8049, Switzerland.

Published: January 2024

Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru-Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (BNH), predominantly BNH, the BN analogue of superbenzene.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10795514PMC
http://dx.doi.org/10.1039/d3cc05709gDOI Listing

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