Electrospun nanofiber membranes have emerged as a novel catalyst, demonstrating exceptional efficacy in advanced oxidation processes (AOPs) for the degradation of organic pollutants. Their superior performance can be attributed to their substantial specific surface area, high porosity, ease of modification, rapid recovery, and unparalleled chemical stability. This paper aims to comprehensively explore the progressive applications and underlying mechanisms of electrospun nanofibers in AOPs, which include Fenton-like processes, photocatalysis, catalytic ozonation, and persulfate oxidation. A detailed discussion on the mechanism and efficiency of the catalytic process, which is influenced by the primary components of the electrospun catalyst, is presented. Additionally, the paper examines how concentration, viscosity, and molecular weight affect the characteristics of the spinning materials and seeks to provide a thorough understanding of electrospinning technology to enhance water treatment methods. The review proposes that electrospun nanofiber membranes hold significant potential for enhancing water treatment processes using advanced oxidation methods. This is attributed to their advantageous properties and the tunable nature of the electrospinning process, paving the way for advancements in water treatment through AOPs.
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http://dx.doi.org/10.1016/j.envpol.2023.123223 | DOI Listing |
Nanomicro Lett
January 2025
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University, Shanghai, 200433, People's Republic of China.
Practical Zn metal batteries have been hindered by several challenges, including Zn dendrite growth, undesirable side reactions, and unstable electrode/electrolyte interface. These issues are particularly more serious in low-concentration electrolytes. Herein, we design a Zn salt-mediated electrolyte with in situ ring-opening polymerization of the small molecule organic solvent.
View Article and Find Full Text PDFChem Rev
January 2025
Department of Chemical & Biomolecular Engineering, University of California, Irvine, California 92697, United States.
The reactions critical for the energy transition center on the chemistry of hydrogen, oxygen, carbon, and the heterogeneous catalyst surfaces that make up electrochemical energy conversion systems. Together, the surface-adsorbate interactions constitute the electrochemical interphase and define reaction kinetics of many clean energy technologies. Practical devices introduce high levels of complexity where surface roughness, structure, composition, and morphology combine with electrolyte, pH, diffusion, and system level limitations to challenge our ability to deconvolute underlying phenomena.
View Article and Find Full Text PDFNano Lett
January 2025
Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China.
The crystalline phase of metal oxides is a key determinant of the properties and functions of the nanomaterials. Traditional approaches have focused on replicating bulk-phase structures, with limited exploration of phase diversity due to challenges in controlling the crystal morphology. Here, we introduce a nanoclay-mediated strategy for crystal-phase engineering, using talc to modulate the morphology and phase of manganese oxide (MnOx) nanoparticles.
View Article and Find Full Text PDFGlob Chang Biol
January 2025
Department of Civil, Environmental, and Geo-Engineering, University of Minnesota, Minneapolis, Minnesota, USA.
Stomata control plant water loss and photosynthetic carbon gain. Developing more generalized and accurate stomatal models is essential for earth system models and predicting responses under novel environmental conditions associated with global change. Plant optimality theories offer one promising approach, but most such theories assume that stomatal conductance maximizes photosynthetic net carbon assimilation subject to some cost or constraint of water.
View Article and Find Full Text PDFLife Med
August 2024
Department of Hepatobiliary Surgery, Xi-Jing Hospital, Fourth Military Medical University, Changle West Road, Xincheng District, Xi'an, Shaanxi 710032, China.
Nonalcoholic fatty liver disease (NAFLD) is the most prevalent chronic liver condition, characterized by a spectrum that progresses from simple hepatic steatosis to nonalcoholic steatohepatitis, which may eventually lead to cirrhosis and hepatocellular carcinoma. The precise pathogenic mechanisms underlying NAFLD and its related metabolic disturbances remain elusive. Epigenetic modifications, which entail stable transcriptional changes without altering the DNA sequence, are increasingly recognized as pivotal.
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