In contemporary times, electromagnetic radiation poses a significant threat to both human health and the normal functioning of electronic devices. Developing composites as adsorption materials possess exceptional electromagnetic wave absorption performances can efficient address this critical issue. Herein, hollow core-shell NiCoO@polypyrrole nanofibers/reduced graphene oxide (NiCo-HFPR) composites are fabricated by the combination of electrostatic spinning, air calcination, in-situ polymerization, freeze-drying and hydrazine vapor reduction. As anticipated, NiCo-HFPR-0.2 exhibits noteworthy properties, with the minimum reflection loss (RL) of -61.20 dB at 14.26 GHz and 1.56 mm, as well as the effective absorption bandwidth (EAB) of 4.90 GHz at 1.57 mm. Additionally, the simulation procedure is employed to determine the radar cross-section (RCS) attenuation. In comparison to a singular perfect electrically conductive (PEC) layer, the PEC layer coated with NiCo-HFPR-0.2 consistently yields an RCS value below -10 dB m within the range of -60° < θ < 60°. The RCS attenuation value of the NiCo-HFPR-0.2 coating achieves an outstanding 31.0 dB m at θ = 0°, strongly affirming the ability to effectively attenuate electromagnetic wave in real-world applications. The employed experimental methodology, the meticulously crafted composite, and the simulation outcomes presented in this study bear great promise for the progressive advancement of both theoretical investigations and practical applications within the domain of electromagnetic wave absorption.
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http://dx.doi.org/10.1016/j.jcis.2023.12.132 | DOI Listing |
Macromol Rapid Commun
January 2025
School of Polymer Science and Engineering, University of Southern Mississippi, Hattiesburg, MS, 39406, USA.
As the demand for clean water intensifies, developing effective methods for removing pollutants from contaminated sources becomes increasingly crucial. This work establishes a method for additive manufacturing of functional polymer sorbents with hollow porous features, designed to enhance interactions with organic micropollutants. Specifically, core-shell filaments are used as the starting materials, which contain polypropylene (PP) as the shell and poly(acrylonitrile-co-butadiene-co-styrene) as the core, to fabricate 3-dimensional (3D) structures on-demand via material extrusion.
View Article and Find Full Text PDFChem Sci
December 2024
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University Nanyang 473601 P. R. China
The conversion of carbon dioxide (CO) into carbon-neutral fuels using solar energy is crucial for achieving energy sustainability. However, the high carrier charge recombination and low CO adsorption capacity of the photocatalysts present significant challenges. In this paper, a TAPB-COF@ZnInS-30 (TAPB-COFZ-30) heterojunction photocatalyst was constructed by growth of ZnInS (ZIS) on a hollow covalent organic framework (HCOF) with a hollow core-shell structure for CO to CO conversion.
View Article and Find Full Text PDFFood Chem
December 2024
Oil Crops Research Institute, Chinese Academy of Agricultural Sciences, Hubei Key Laboratory of Lipid Chemistry and Nutrition, Hubei Hongshan Laboratory, Key Laboratory of Oilseeds Processing, Ministry of Agriculture, Wuhan 430062, China; Xinjiang Uygur Autonomous Region Saihu Fishery Science and Technology Development Company Limited, Bortala Mongol Autonomous Prefecture, 833500, China. Electronic address:
ACS Appl Mater Interfaces
December 2024
Centre for Cell Factories and Biopolymers, Griffith Institute for Biomedicine and Glycomics, Griffith University, Nathan, QLD 4111, Australia.
Bacterial cell factories have been successfully engineered to efficiently assemble spherical polyhydroxybutyrate inclusions coated with functional proteins of interest. In these submicrometer-sized core-shell assemblies, proteins are bioconjugated to the polymer core, enabling bioengineering for uses as bioseparation resins, enzyme carriers, diagnostic reagents, and particulate vaccines. Here, we explore whether these functional protein-polymer assemblies could be restructured via dissolution and subsequent precipitation while retaining the functionality of the conjugated protein.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 610054, China.
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