AI Article Synopsis
- Perovskite nanocrystals (NCs) are promising materials for electronic devices due to their high efficiency but face challenges with stability and surface quality.
- A new strategy inspired by drug delivery systems involves doping Ag into CsPbBr (CPB) NCs to enhance their structural stability by targeting and repairing defects.
- Experimental and theoretical analyses show that this approach improves the optical properties of the NCs, making them suitable for applications like white light-emitting diodes.
Article Abstract
Perovskite nanocrystals (NCs) have emerged as a promising building block for the fabrication of optic-/optoelectronic-/electronic devices owing to their superior characteristics, such as high absorption coefficient, rapid ion mobilities, and tunable energy levels. However, their low structural stability and poor surface passivation have restricted their application to next-generation devices. Herein, a drug delivery system (DDS)-inspired post-treatment strategy is reported for improving their structural stability by doping of Ag into CsPbBr (CPB) perovskite NCs; delivery to damaged sites can promote their structural recovery slowly and uniformly, averting the permanent loss of their intrinsic characteristics. Ag NCs are designed through surface-chemistry tuning and structural engineering to enable their circulation in CPB NC dispersions, followed by their delivery to the CPB NC surface, defect-site recovery, and defect prevention. The perovskite-structure healing process through the DDS-type process (with Ag NCs as the drug) is analyzed by a combination of theoretical calculations (with density functional theory) and experimental analyses. The proposed DDS-inspired healing strategy significantly enhances the optical properties and stability of perovskite NCs, enabling the fabrication of white light-emitting diodes.
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| http://dx.doi.org/10.1002/smll.202307032 | DOI Listing |
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