Despite the extensive use of engineered hydrochar (EHC) for contaminants adsorption in water, little is known about the scaling-up of EHC production which has kept the technology at a low readiness level (TRL). Full-scale EHC production was simulated to help bridge this knowledge gap. A systematic analysis was performed where EHC was produced from rice straw using hydrothermal carbonization (HTC) at 200 °C with iron addition. A techno-economic evaluation model was employed to simulate the production process and to estimate energy requirements, configuration, and cost scenarios for the HTC process. The minimum selling price (MSP) analysis of the engineered hydrochar was found to be almost half compared to the market price for other similar sorbents ($ 76/t vs. $136/t) suggesting that EHC production is feasible for scaling up. Finally, as a trial, the resulting material was tested for its efficacy in the adsorption of an anionic organic contaminant (e.g., Congo Red, CHNNaOS) in water to identify its potential for water treatment. Experimental results showed that EHC adsorbed > 95% CR suggesting significant adsorption capability and feasibility for production scale-up.
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http://dx.doi.org/10.1016/j.wasman.2023.12.024 | DOI Listing |
Environ Res
January 2025
Thermochemical Processes Group, Aragón Institute for Engineering Research (I3A), University of Zaragoza, C/Mariano Esquillor s/n, 50.018, Zaragoza, Spain. Electronic address:
This work explores the synergies between N-rich (Chlorella pyrenoidosa) microalgae and N-deficient (Undaria pinnatifida) macroalgae for the production of N-containing hydrochar and solid biofuels via co-hydrothermal carbonization (co-HTC). The impact of the feedstock (each alga alone and all possible binary mixtures) was comprehensively assessed under different temperatures (180-260 °C) and times (60-240 min). The synergies between micro and macroalgae governed product distribution, nitrogen transformation pathways, and hydrochar quality, with these effects varying by processing conditions.
View Article and Find Full Text PDFWaste Manag
December 2024
Key Laboratory of Agro-Environment in Downstream of Yangtze Plain/Scientific Observing and Experimental Station of Arable Land Conservation (Jiangsu), Ministry of Agriculture and Rural Affairs, Institute of Agricultural Resources and Environment, Jiangsu Academy of Agricultural Sciences, Nanjing 210014, China. Electronic address:
Water Sci Technol
December 2024
Water Research Commission, Lynnwood Bridge Office Park, 2nd Floor, Bloukrans Building, 4 Daventry Street, Lynnwood Manor, Pretoria 0081, South Africa; Water Utilisation and Environmental Engineering Division, Department of Chemical Engineering, University of Pretoria, Pretoria 0002, South Africa E-mail:
The management of municipal wastewater sludge is a significant challenge for wastewater management, particularly the need to manage and dispose of the sludge in an environmentally friendly and sustainable manner. The emergence of stricter regulations regarding landfill disposal of wastewater sludge necessitates the need for alternative options for municipal wastewater sludge management, with thermochemical technologies potentially contributing towards achieving carbon neutrality goals and fostering sustainable development. This study sought to address these challenges through a technical and financial evaluation of a pilot-scale emerging thermochemical technology, the enhanced hydrothermal polymerization to provide adequate understanding of the technology's feasibility regarding its application for municipal wastewater sludge volarization into a multi-use hydrochar.
View Article and Find Full Text PDFHeliyon
December 2024
School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.
In this study, modeling and optimization of Hydrothermal Carbonization (HTC) of Poultry litter were conducted to convert it into high-value materials. The aim was to understand the process and predict the effect of the influencing parameters on the product properties. The recovery of Inorganic Phosphorous (IP) and Carbon (C) was regarded as the model's response, although temperature and reaction time were thought to be important variables.
View Article and Find Full Text PDFEnviron Res
December 2024
School of Resources and Environment, Northeast Agricultural University, Harbin, 150030, China. Electronic address:
Nitrogen-doped porous hydrochar (NPHC) was successfully synthesized by hydrothermal carbonization and activation with KHCO, which was employed for scavenging hexavalent chromium (Cr(VI)) and bisphenol A (BPA) in contaminated water. N doping increased the unique active sites such as amino and molecular N in NPHC for adsorbing contaminants, and enhanced the activation effect. Compared to original (HC) and N-doped hydrochar (NHC), the S of material improved from 3.
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