AI Article Synopsis
- Phosphine-functionalized metal-organic frameworks (P-MOFs) are a new type of coordination polymer that offer potential for creating heterogeneous catalysts, but their development is still in its early stages compared to traditional homogeneous phosphine systems.
- This review summarizes the methods for synthesizing P-MOFs, their characterization, and their performance in various catalytic reactions while examining the relationship between phosphine ligand structure and function.
- The article also identifies challenges facing the development of P-MOF catalysts and suggests potential solutions, including exploring new reactions and innovative techniques.
Article Abstract
Phosphine-functionalized metal-organic frameworks (P-MOFs) as an emerging class of coordination polymers, have provided novel opportunities for the development of heterogeneous catalysts. Yet, compared with the ubiquitous phosphine systems in homogeneous catalysis, heterogenization of phosphines in MOFs is still at its early stage. In this Minireview, we summarize the synthetic strategies, characterization and catalytic reactions based on the P-MOFs reported in literature. In particular, various catalytic reactions are discussed in detail in terms of phosphine ligand structure-function relationship, including the potential obstacles for future development. Finally, we discuss the possible solutions, including new types of reactions and techniques as the perspectives for the development of P-MOF catalysts, highlighting the opportunities and challenges.
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| http://dx.doi.org/10.1002/anie.202315075 | DOI Listing |
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