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| http://dx.doi.org/10.1186/s13054-023-04772-4 | DOI Listing |
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Contribution of Weak Bases to Isoxaflutole Hydrolysis: Implications for Hydrolysis in Laboratory and Natural Waters.
Environ Sci Technol
January 2025
Department of Energy, Environmental & Chemical Engineering Washington University in St. Louis, St. Louis, Missouri 63130, United States.
The hydrolysis rates of many organic chemicals are accelerated under alkaline conditions by the presence of hydroxide (HO), which is typically assumed to be the predominant species contributing to base-catalyzed hydrolysis in both natural waters and laboratory buffers used in standard protocols. In this study, we demonstrated that weak bases (e.g.
View Article and Find Full Text PDFDo coastal salt mudflats (sabkhas) contribute to the blue carbon sequestration?
Biogeochemistry
January 2025
Environmental Science Center, Qatar University, P.O. Box 2713, Doha, Qatar.
Unlabelled: Blue carbon represents the organic carbon retained in marine coastal ecosystems. (an Arabic for "mudflats"), formed in tidal environments under arid conditions, have been proposed to be capable of carbon sequestrating. Despite the growing understanding of the critical role of blue carbon ecosystems, there is a current dispute about whether sabkhas around the Persian Gulf can contribute to carbon retention as a blue carbon ecosystem.
View Article and Find Full Text PDFWithout visual feedback voluntary torque is overestimated during muscle potentiation despite similar motor unit firing rate and perception of exertion.
J Neurophysiol
January 2025
School of Kinesiology, Faculty of Health Sciences, The University of Western Ontario, London, ON, Canada.
The purpose was to assess whether visual feedback of torque contributes to motor unit (MU) firing rate reduction observed during post-activation potentiation (PAP) of skeletal muscle. From 15 participants 23 MUs were recorded with intramuscular fine-wire electrodes from the tibialis anterior during isometric dorsiflexion contractions at 20% of maximum, with and without both PAP and visual feedback of torque. A 5s maximal voluntary contraction (MVC) was used to induce PAP, and evoked twitch responses were assessed before and after.
View Article and Find Full Text PDFModeling and Elucidating the Behavior of a Thermoresponsive LCST Ionic Liquid.
J Chem Inf Model
January 2025
Donostia International Physics Center (DIPC), 20018 Donostia-San Sebastián, Spain.
Desalination of seawater by forward osmosis is a technology potentially able to address the global water scarcity problem. The major challenge limiting its widespread practical application is the design of a draw solute that can be separated from water by an energetically efficient process and then reused for the next cycle. Recent experiments demonstrate that a promising draw solute for forward-osmosis desalination is tetrabutylphosphonium 2,4,6-trimethylbenzenesulfonate ([P][TMBS]).
View Article and Find Full Text PDFOutcomes After Thoracoscopic and Open Repair of Esophageal Atresia With Tracheoesophageal Fistula at US Children's Hospitals.
J Pediatr Surg
December 2024
Rady Children's Hospital San Diego, 3020 Children's Way, San Diego, CA 92123, USA; University of California San Diego School of Medicine, Department of Surgery, 9500 Gilman Dr., La Jolla, CA 92093, USA. Electronic address:
Background: Thoracoscopic repair of esophageal atresia with tracheoesophageal fistula (EA/TEF) has been reported to have superior outcomes to the open approach. We sought to evaluate adoption of thoracoscopic repair at US children's hospitals and compare outcomes to open repair.
Methods: The Pediatric Health Information System database was used to identify patients with EA/TEF who underwent repair between 2016 and 2023.
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