We have observed the transient dynamics in nematic electroconvection during a sudden change in the driving voltage. The steady state dynamics of nematic electroconvection during a constant driving voltage are well characterized examples of spatiotemporal chaos, and thus are useful for the study of chaotic transients. For a set of starting conditions, we were able to show that the system can enter a long-lived transient state with a larger power dissipation rate. This transient state decays through the skew varicose instabilities into steady state defect turbulence. We observed the onset of both Eckhaus and skew varicose instabilities, interpret this transition in the framework of dynamical crisis, and quantify the transition through the evolution of the information entropy in the images as well as the power dissipated by the sample. We identify this long-lived but transient state as originating from the structure of the convective rolls in the initial state and hypothesize that the exploitation of transient states such as these may occur in natural systems and could be leveraged for industrial processing.
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http://dx.doi.org/10.1063/5.0063131 | DOI Listing |
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January 2025
Department of Chemical Engineering, University of South Carolina, Columbia, SC, 29208, USA.
Precisely crafted hierarchical architectures found in naturally derived biomaterials underpin the exceptional performance and functionality showcased by the host organism. In particular, layered helical assemblies composed of cellulose, chitin, or collagen serve as the foundation for some of the most mechanically robust and visually striking natural materials. By utilizing structured materials in additive manufacturing techniques such as extrusion-based 3D printing, the intrinsic deformation process can be used to implement bottom-up design of printed constructs, offering the potential to create intricate macroscale geometries with embedded nanoscale functionality.
View Article and Find Full Text PDFACS Nano
January 2025
Centre de recherche du Centre hospitalier de l'Université de Montréal (CRCHUM), Montréal, Québec H2X 0A9, Canada.
The abnormally viscous and thick mucus is a hallmark of cystic fibrosis (CF). How the mutated CF gene causes abnormal mucus remains an unanswered question of paramount interest. Mucus is produced by the hydration of gel-forming mucin macromolecules that are stored in intracellular granules prior to release.
View Article and Find Full Text PDFMater Horiz
January 2025
Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, China.
Dynamic responsive structural colored materials have drawn increased consideration in a wide range of applications, such as colorimetric sensors and high-safety tags. However, the sophisticated interactions among the individual responsive parts restrict the advanced design of multimodal responsive photonic materials. Inspired by stimuli-responsive color change in chameleon skin, a simple and effective photo-crosslinking strategy is proposed to construct hydroxypropyl cellulose (HPC) based hydrogels with multiple responsive structured colors.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical and Biological Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK S7N 5A9, Canada. Electronic address:
This study explores the effect of sucrose addition on the properties of chiral nematic cellulose nanocrystal (CNC) films for potential food industry applications, including biodegradable packaging and food coloring. The addition of sucrose altered the films' structural color, shifting from blue in pure CNC films to aqua blue, green, yellow-green, and red with increasing sucrose concentrations (up to 21 %). Surface analysis revealed a reduction in contact angle from 96° to 48° due to sucrose's hydrophilic nature and smoother film surfaces.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Department of Physical and Colloid Chemistry, Kazan National Research Technological University, 420015 Kazan, Russia.
Microfluidics provides cutting-edge technological advancements for the in-channel manipulation and analysis of dissolved macromolecular species. The intrinsic potential of microfluidic devices to control key characteristics of polymer macromolecules such as their size distribution requires unleashing its full capacity. This work proposes a combined approach to analyzing the microscale behavior of polymer solutions and modifying their properties.
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