AI Article Synopsis
- An iodine-mediated process was developed to synthesize 6-alkylthio-1,3,5-triazine-2,4-diamines using -alkylpyridinium salts and NHSCN in air.
- A total of 27 different compounds were successfully produced under these standard reaction conditions.
- Pyridinium salts facilitate the formation of the C-S bond, which is essential for building the triazine structure, and a proposed mechanism is outlined based on experiments and existing literature.
Article Abstract
An iodine-mediated method for the synthesis of 6-alkylthio-1,3,5-triazine-2,4-diamines by the reaction of -alkylpyridinium salts and NHSCN in air is reported. Twenty-seven compounds were obtained under the standard conditions. Pyridinium salts work as benzyl-group transfer reagents to promote the formation of the C-S bond and thereby the construction of the triazine skeleton. A plausible mechanism is proposed based on the experimental results and literature survey.
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| http://dx.doi.org/10.1021/acs.joc.3c02517 | DOI Listing |
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