An electrochemical sensor based on carbon composites derived from bisbenzimidazole biphenyl coordination polymers for dihydroxybenzene isomers detection.

Co-based coordination polymers (CoCP) based on 4,4'-bis(1H-benzo[d]imidazol-1-yl)-1,1'-biphenyl (BMB) ligand have been synthesized for the first time by the solvothermal method. The CoCP was carbonized at 700 °C under a nitrogen atmosphere to obtain carbide coordination polymer (C-CoCP) with a unique two-dimensional layered network structure. C-CoCP@GO was obtained by binding with GO and C-CoCP, its morphology and structure were investigated by XRD, SEM, EDS, FTIR, and TGA, which confirmed its two-dimensional stacked layered structure with high catalytic activity and large specific surface area. A highly sensitive electrochemical sensor was constructed for the simultaneous detection of hydroquinone and catechol based on the prepared carbon-based composite. Under optimized conditions, the working potentials (vs. Ag/AgCl) of HQ and CC are at 0.097 V and 0.213 V, respectively. The sensor exhibited an extremely wide linear range of 3-600 μM and 3-1750 μM for hydroquinone (HQ) and catechol (CC), respectively, with limits of detection (LOD) of 0.46 μM and 0.27 μM. The electrode material demonstrated stability over 14 days without significant attenuation of the response signal. Impressively, the sensor shows high stability, reproducibility, and selectivity due to the stable carbon skeleton structure of the C-CoCP material. In addition, it can be applied to the detection of hydroquinone in real samples with high interference immunity and high recovery. Hence, the C-CoCP@GO composite proved to be a great prospect and highly sensitive sensing platform for the detection of phenolic isomers.