Ti C T Quantum dots (QDs)/L-Ti C T fiber electrode (Q M ) with high capacitance and excellent flexibility is prepared by a wet spinning method. The assembled units Ti C T nanosheets (NSs) with large size (denoted as L-Ti C T ) is obtained by natural sedimentation screen raw Ti AlC , etching, and mechanical delamination. The pillar agent Ti C T QDs is fabricated by an ultrasound method. Q M fiber electrode gave a specific capacitance of 1560 F cm , with a capacity retention rate of 79% at 20 A cm , and excellent mechanical strength of 130 Mpa. A wide temperature all-solid-state the delaminated montmorillonite (F-MMT)/Polyvinyl alcohol (PVA) dimethyl sulfoxide (DMSO) flexible hydrogel (DHGE) (F-MMT/PVA DHGE) Q M fiber supercapacitor is assembled by using Q M fiber as electrodes and F-MMT/PVA DHGE as electrolyte and separator. It showed a volume specific capacitance of 413 F cm at 0.5 A cm , a capacity retention of 97% after 10 000 cycles, an energy density of 36.7 mWh cm at a power density of 311 mW cm , and impressive capacitance and flexibility over a wide temperature range of -40 to 60 °C. This work provides an effective strategy for designing and assembling wide temperature all-solid-state fiber supercapacitors with optimal balance of capacitive performance and flexibility.
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http://dx.doi.org/10.1002/advs.202305991 | DOI Listing |
Sci Rep
December 2024
Laboratorio de Fluidodinámica, Facultad de Ingeniería, Universidad de Buenos Aires/CONICET, Paseo Colón 850 CABA, Buenos Aires, Argentina.
The oil and gas industry faces two significant challenges, including rising global temperatures and depletion of reserves. Enhanced recovery techniques such as polymer flooding have positioned themselves as an alternative that attracts international attention thanks to increased recovery factors with low emissions. However, existing physical models need further refinement to improve predictive accuracy and prevent design failures in polymer flooding projects.
View Article and Find Full Text PDFNat Commun
December 2024
Institute of Carbon Neutrality, Sino-French Institute for Earth System Science, College of Urban and Environmental Sciences, Peking University, Beijing, China.
Compound soil drought and heat extremes are expected to occur more frequently with global warming, causing wide-ranging socio-ecological repercussions. Vegetation modulates air temperature and soil moisture through biophysical processes, thereby influencing the occurrence of such extremes. Global vegetation cover is broadly expected to increase under climate change, but it remains unclear whether vegetation greening will alleviate or aggravate future increases in compound soil drought-heat events.
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December 2024
Key Laboratory of Advanced Polymeric Materials of Shanghai, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, P. R. China.
As integrated circuits have developed towards the direction of complexity and miniaturization, there is an urgent need for low dielectric constant materials to effectively realize high-fidelity signal transmission. However, there remains a challenge to achieve ultralow dielectric constant and ultralow dielectric loss over a wide temperature range, not to mention having excellent thermal conductivity and processability concurrently. We herein prepare dual-linker freestanding covalent organic framework films with tailorable fluorine content via interfacial polymerization.
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December 2024
Department of Chemical Engineering, Electrochemical Innovation Lab, University College London, London, UK.
High-temperature proton exchange membrane fuel cells (HT-PEMFCs) offer solutions to challenges intrinsic to low-temperature PEMFCs, such as complex water management, fuel inflexibility, and thermal integration. However, they are hindered by phosphoric acid (PA) leaching and catalyst migration, which destabilize the critical three-phase interface within the membrane electrode assembly (MEA). This study presents an innovative approach to enhance HT-PEMFC performance through membrane modification using picosecond laser scribing, which optimises the three-phase interface by forming a graphene-like structure that mitigates PA leaching.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Institute for Frontier Materials, Deakin University, Geelong, Victoria, 3220, Australia.
Two-dimensional (2D) nanochannels have demonstrated outstanding performance for sieving specific molecules or ions, owing to their uniform molecular channel sizes and interlayer physical/chemical properties. However, controllably tuning nanochannel spaces with specific sizes and simultaneously achieving high mechanical strength remain the main challenges. In this work, the inter-sheet gallery d-spacing of graphene oxide (GO) membrane is successfully tailored with high mechanical strength via a general radical-induced polymerization strategy.
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