Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 176
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Detection of toxic hydrazine and harmful strong acidity is of great importance for survival of organisms. In the present paper, a new thiomorpholine substituted malonyl-coumarin dye was synthesized for discriminative detection of hydrazine and strong acidity. At pH 7.4, the fluorescence at 560 nm decreased and that at 496 nm increased upon reaction with hydrazine, which was used for on-site detection of hydrazine vapor and endogenous hydrazine in live cells. From pH 2.0 to 1.2, the fluorescence at 563 nm increased greatly, which could be ascribed to the PET process from thiomorpholine to malonyl-coumarin. The probe was desirable for discriminative detection of toxic hydrazine and strong acidity.
Download full-text PDF |
Source |
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10704299 | PMC |
http://dx.doi.org/10.1039/d3ra07183a | DOI Listing |
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