The substitution of chemical nitrogen fertilizer with manure holds the potential for a synergistic rise in wheat grain yield and protein concentration, while minimizing residual nitrate in soil. We conducted a 6-year field fertilization experiment including two manure treatments (with or without) and five nitrogen applications rates (0, 60, 120, 180 and 240 kg ha). The study investigated the impact of single chemical nitrogen (CN) and manure substitution for nitrogen fertilizer (MN) on the grain yield (GY), grain protein concentration (GPC), plant nitrogen uptake (PNupt) and plant nitrogen requirement (PNR) of wheat, and the dynamic change of soil nitrate-N. The findings revealed that: (1) the MN demonstrated a greater advantage over CN, as evidenced by a 13.4-16.0 % increase in GY, a 2.6-3.8 % increase in GPC, a 7.2-15.7 % increase in PNupt and a 1.5-4.7 % reduction in PNR. (2) Soil nitrate accumulation (SNA) significantly increased when fertilizer rates ≥180 kg ha and the peak annually shifted to deeper layer. The MN increased the SNA by 20.9-21.8 %, but significantly reduced SNA by 11.8-13.5 % compared with the CN. Topsoil nitrate content (SNC) can be adopted as a substitute for SNA to make the fertilization schedule convenient. (3) Regression analysis revealed (taking the MN for example) that the optimum N rates for the maximum GY (5417 kg ha) and GPC (15.3 %) were 164 and 211 kg N ha, respectively. The nitrate-N safety threshold was 62 kg ha at the fertilizer rate of 89 kg N ha. Based on this, nitrogen fertilizer input reduced by 44.8-57.2 % and SNA by 17.9-33.6 %, with achieving 91.8-95.0 % of maximum GY and 89.7-92.9 % of maximum GPC. Substituting manure for nitrogen fertilizer achieved the potential of maintaining the grain yield and protein concentration while the minimization in soil nitrate residue. This study offers a feasible way for fertilization recommendation and nitrate residue controlling in dry farming.
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http://dx.doi.org/10.1016/j.scitotenv.2023.169238 | DOI Listing |
JACS Au
December 2024
State Key Laboratory of Fine Chemicals, School of Chemistry, Dalian University of Technology, Dalian 116024, China.
Nitroaromatics, as an important member and source of nitrogen-containing aromatics, is bringing enormous economic benefits in fields of pharmaceuticals, dyes, pesticides, functional materials, fertilizers, and explosives. Nonetheless, the notoriously polluting nitration industry, which suffers from excessive discharge of fumes and waste acids, poor functional group tolerance, and tremendous purification difficulty, renders mild, efficient, and environmentally friendly nitration a formidable challenge. Herein, we develop a visible-light-driven biocompatible arene C-H nitration strategy with good efficiency and regioselectivity, marvelous substrate applicability and functional group tolerance, and wide application in scale-up synthesis, total synthesis, and late-stage functionalization.
View Article and Find Full Text PDFPeerJ
December 2024
Field Crops/Agricultural Faculty, Ordu University, Ordu, Turkey.
It is very important to determine the chlorophyll content (SPAD) and nitrogen (N) requirement in order to increase the seed yield and nutritional quality of wheat. This research was carried out with three N doses (0, 50, 100 kg ha) and nine wheat cultivars (Alpu-2001, Soyer-02, Kate-A1, Bezostaja-1, Altay-2000, Müfitbey, Nacibey, Harmankaya-99 and Sönmez-2001) during 2-years field condition according to factorial randomized complete block design and three replications. In this study, with the increase of N dose (N50), seed yield increased by 13%, plant height by 10.
View Article and Find Full Text PDFEnviron Pollut
December 2024
College of Resources and Environmental Sciences, National Academy of Agriculture Green Development, State Key Laboratory of Nutrient Use and Management, National Observation and Research Station of Agriculture Green Development (Quzhou, Hebei), China Agricultural University, Beijing 100193, China. Electronic address:
Poor management of nitrogen (N) can lead to serious environmental problems, such as air and water pollution. The accurate identification of priority control areas and emission sources is critical for making effective decisions regarding sustainable N management. This study aimed to identify hotspots for N losses and quantitatively analyze the relative contributions of different emission sources in the Huang-Huai-Hai Basin at the county scale.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Institute of Chemistry, Federal University of Mato Grosso do Sul, Avenida Senador Filinto Muller 1555, Campo Grande, Mato Grosso do Sul 79074-460, Brazil.
There has been huge interest among chemical scientists in the electrochemical reduction of nitrate (NO) to ammonia (NH) due to the useful application of NH in nitrogen fertilizers and fuel. To conduct such a complex reduction reaction, which involves eight electrons and eight protons, one needs to develop high-performance (and stable) electrocatalysts that favor the formation of reaction intermediates that are selective toward ammonia production. In the present study, we developed and applied CoO/graphene nanoribbon (GNR) electrocatalysts with excellent properties for the effective reduction of NO to NH, where NH yield rate of 42.
View Article and Find Full Text PDFYing Yong Sheng Tai Xue Bao
October 2024
State Key Laboratory for Managing Biotic and Chemical Threats to the Quality and Safety of Agro-products, Institute of Plant Virology, Ningbo University, Ningbo 315211, Zhejiang, China.
Fruit quality and yield in orchards will decrease after long-term planting. To analyze the changes of soil quality under different planting years and identify the key factors of the declining of orchard soil quality could provide scientific foundation for optimizing fertilization management of orchard soil. In this study, we analyzed the changes of soil physical, chemical, and biological properties of loquat orchard under different planting years (<10 years, 10-15 years, 15-20 years, ≥20 years) in Ninghai County, Zhejiang Province, and evaluated soil health by using soil quality index, multifunctionality index, and sensitivity and resistance indicators.
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