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There is much interest in developing metal-free halogenated graphene such as fluorinated graphene for various catalytic applications. In this work, a fluorine-doped graphene oxide photocatalyst was investigated for photocatalytic oxidation (PCO) of a volatile organic compound (VOC), namely gaseous methanol. The fluorination process of graphene oxide (GO) was carried out via a novel and facile solution-based photoirradiation method. The fluorine atoms were doped on the surface of the GO in a semi-ionic C-F bond configuration. This presence of the semi-ionic C-F bonds induced a dramatic 7-fold increment of the hole charge carrier density of the photocatalyst. The fluorinated GO photocatalyst exhibited excellent photodegradation up to 93.5% or 0.493 h according pseudo-first order kinetics for methanol. In addition, 91.7% of methanol was mineralized into harmless carbon dioxide (CO) under UV-A irradiation. Furthermore, the photocatalyst demonstrated good stability in five cycles of methanol PCO. Besides methanol, other VOCs such as acetone and formaldehyde were also photodegraded. This work reveals the potential of fluorination in producing effective graphene-based photocatalyst for VOC removal.
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http://dx.doi.org/10.1016/j.chemosphere.2023.140890 | DOI Listing |
Chem Sci
December 2024
Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences Beijing 100190 China
Nanofluidics is a system of fluid transport limited to a nano-confined space, including the transport of ions and molecules. The use of intelligent nanofluidics has shown great potential in energy conversion. However, ion transport is hindered by homogeneous membranes with uniform charge distribution and concentration polarization, which often leads to an undesirable power conversion performance.
View Article and Find Full Text PDFHeliyon
December 2024
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, 010021, China.
Graphene and its derivatives are widely used in various fields due to their unique two-dimensional lamellar structure. This study aims to synthesize ultra-large graphene oxide (GO) sheets from natural flake graphite and investigate the factors influencing their size. Using a two-intercalation method based on the modified Hummers' method, we address the challenge of intercalating large-diameter graphene oxide by employing a secondary intercalation technique.
View Article and Find Full Text PDFMicrosyst Nanoeng
December 2024
Key Laboratory of MEMS of the Ministry of Education, Southeast University, Nanjing, 210096, China.
Piezoelectric resonance sensors are essential to many diverse applications associated with chemical and biological sensing. In general, they rely on continuously detecting the resonant frequency shift of piezoelectric resonators due to analytes accreting on their surfaces in vacuum, gas or fluid. Resolving the small analyte changes requires the resonators with a high quality factor.
View Article and Find Full Text PDFNanotechnology
December 2024
Donghua University, 1882 West Yan'an Road, Shanghai, 200051 , CHINA.
To advance the industrialization of flexible strain sensors, an innovative flexible sensing fiber was developed through a sophisticated wet spinning process. Silver trifluoroacetate (C2AgF3O2) and graphene oxide (GO) were combined with thermoplastic polyurethane (TPU) to prepare the fibers via wet spinning. Ascorbic acid (L-AA) was used to in situ reduce the silver trifluoroacetate and graphene oxide within the polyurethane, causing the growth of silver nanoparticles to bond with reduced graphene oxide, forming a dual conductive pathway.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China. Electronic address:
Thermal batteries are a type of thermally activated reserve batteries, where the cathode material significantly influences the operating voltage and specific capacity of the battery. In this work, VS-VO has been synthesized through the hydrothermal method and used as the cathode material for thermal batteries. Firstly, the material with the VS crystallinity is obtained at 170 °C and the mass percentages of VS/VO are 63.
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