Laminate substrates in advanced IC packages serve as not only the principal heat dissipation pathway but also the critical component governing the thermomechanical performance of advanced packaging technologies. A solid and profound grasp of their thermomechanical properties is of crucial importance to better understand IC packages' thermomechanical behavior. This study attempts to introduce a subregion homogenization modeling framework for effectively and efficiently modeling and characterizing the equivalent thermomechanical behavior of large-scale and high-density laminate substrates comprising the non-uniform distribution and non-unidirectional orientation of tiny metal traces. This framework incorporates subregion modeling, trace mapping and modeling, and finite element analysis (FEA)-based effective modeling. In addition, the laminates are macroscopically described as elastic orthotropic or elastic anisotropic material. This framework is first validated with simple uniaxial tensile and thermomechanical test simulations, and the calculation results associated with these two effective material models are compared with each other, as well as with those of two existing mixture models, and direct the detailed FEA. This framework is further tested on the prediction of the process-induced warpage of a flip chip chip-scale package, and the results are compared against the measurement data and the results of the whole-domain modeling-based effective approach and two existing mixture models.
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http://dx.doi.org/10.3390/ma16237491 | DOI Listing |
ACS Appl Mater Interfaces
March 2025
School of Materials Science and Engineering, Guangdong Provincial Engineering Technology Research Center of Key Material for High Performance Copper Clad Laminate, Dongguan University of Technology, Dongguan 523808, China.
A series of tertiary amine suspended hyper-cross-linked ionic polymers (HCIPs), characterized by a rich mesoporous structure, high ionic liquid (IL) density, and good CO adsorption capability, were readily prepared via a postsynthetic method. The self-polymerization of 1,3,5-tris(bromomethyl) benzene (TBB) or its copolymerization with 4,4'-bis(bromomethyl) biphenyl (BBP) in varying ratios, followed by grafting with ,,','-tetramethyl-1,3-propanediamine (TMPDA), yielded the target TMPDA-HCIPs. These HCIPs constitute one of the limited categories of heterogeneous water-tolerant catalyst types ever developed for the cycloaddition reaction between CO and epoxides.
View Article and Find Full Text PDFSmall
March 2025
Department of Chemistry & Biochemistry, Kent State University, Kent, OH, 44242, USA.
Specificity and activity are often at odds for natural enzymes. In this work, specificity and activity in coronazymes made of an Au nanoparticle (AuNP) and coated with DNA aptamer for glucose substrates are decoupled. By single-molecule fluorescent MT-HILO (magnetic tweezers coupled with highly inclined and laminated optical sheet) microscopy, it is found that this coronazyme has ≈30 times higher activity on the d-glucose compared to bare AuNP nanozymes.
View Article and Find Full Text PDFSmall
February 2025
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing, 210009, China.
Aprotic Li-O batteries exhibit ultra-high energy density through the redox reaction of O. However, their open-structure design makes them prone to water infiltration and electrolyte leakage. Traditionally, dense and thick oxygen-permeable membranes (OPMs) are employed to prevent HO intrusion, but this approach limits O permeance and constrains charge current densities.
View Article and Find Full Text PDFPolymers (Basel)
February 2025
Departamento de Engenharia Mecânica, Faculdade de Engenharia (FEUP), Universidade Do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal.
The use of adhesive bonding for joining composites has grown due to its excellent performance compared to traditional joining methods. However, delamination remains a significant issue in adhesively bonded composite joints, often causing early failure and reducing joint performance. To address this, there is a strong interest in methods that enhance the through-thickness strength of composite substrates to reduce the risk of delamination.
View Article and Find Full Text PDFMembranes (Basel)
January 2025
Centre for Advanced 2D Materials, National University of Singapore, Singapore 117546, Singapore.
The large-scale implementation of 2D material-based membranes is hindered by mechanical stability and mass transport control challenges. This work describes the fabrication, characterisation, and testing of self-standing graphene oxide (GO) membranes cross-linked with oxides such as FeO, AlO, CaSO, NbO, and a carbide, SiC. These cross-linking agents enhance the mechanical stability of the membranes and modulate their mass transport properties.
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