AI Article Synopsis
- The study presents the creation of stable organometallic Au(III) polymer reagents that can be used for specific chemical reactions.
- These reagents are effective in selectively attaching aromatic groups to small molecules and polymers containing thiol groups, resulting in new functionalized polymers.
- The reactions are quick and yield complete conversions, highlighting the method's efficiency and usefulness in polymer modification.
Article Abstract
Herein, we describe the synthesis of bench-stable organometallic Au(III) terminated polymer reagents. These reagents mediate the chemoselective -arylation of thiol-containing small molecules and polymers to yield functionalized mono-telechelic polymers and diblock copolymers, respectively. These transformations proceed rapidly within minutes and produce conjugates in quantitative conversion, making this strategy a robust addition to the polymer functionalization toolbox.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11149381 | PMC |
| http://dx.doi.org/10.1039/d3cc05350d | DOI Listing |
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