Novel supramolecular (SCPs) compounds such as: {[Ni (EIN)(NCS)]}, SCP1 and {[Co (EIN) (NCS)]}, SCP2 have been studied using weight loss (WL) and electrochemical tests on the corrosion performance of stainless steel 304 (SS304) in 1.0 M hydrochloric acid (HCl) solution. The experimental results revealed that inhibition efficacy (%) rises with increasing concentrations of SCPs and reached 92.3% and 89.6% at 16 × 10 M, 25 °C, from the WL method for SCP1 and SCP2, respectively. However, by raising the temperature, % was reduced. Polarization measurements (PDP) showed that the SCPs molecules represent a mixed-type. The SCPs were adsorbed on a SS304 surface physically, and the Langmuir adsorption isotherm was found to govern the adsorption process. The determination of thermodynamic parameters was carried out at various temperatures. Quantum chemical calculations were calculated to prove the adsorption process of SCP components, using the molecular dynamics (MD) simulations and electron density map. The inhibition performance of SCPs for SS304 dissolution in an acidic medium was proved to be excellent through FT-IR and AFM analysis. The results obtained from all measurements exhibit a high level of agreement with each other.
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| http://dx.doi.org/10.1039/d3ra07397a | DOI Listing |
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