The purpose of this paper is to propose a new methodology to devise a custom-made hydrogen-based proton-exchange membrane fuel cell (PEMFC) system for a class of experimental fixed-wing small unmanned aerial vehicles (SUAVs). The proposed fuel cell provides three times higher flight endurance than the conventional battery-based powertrain. The chosen SUAV represents a class of high-altitude UAVs, having an operational altitude of 4500 m (14,760ft), cruising speed of 12-20 m/s (39.4-65.6 ft/s), take-off weight of 4 kg, wing-span of 1.61 m (5.28 ft) and battery-powered flight endurance of 1 h. The characteristic parameters and design configurations of the fuel cell are determined by employing the first principles of electrochemistry and thermodynamics. Corresponding simulations are performed using popular development tools like MATLAB/Simulink. The vital results in the form of - polarization and power curves for fuel cells, against the current density are obtained, which are further narrowed down to meet the target power requirements for determining the size of the hydrogen storage tank. The paper also comments on the auxiliary systems and fuel cell powertrain for SUAVs. Finally, the design efficiency of 54% for the fuel cell is achieved with respect to equivalent voltage for heating value with the calculated hydrogen storage tank size of 5.688 ls. This yields three times higher flight endurance as compared to the flight time found in literature for the same class of SUAVs.
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Anal Chem
January 2025
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, PR China.
Wearable sensors have broad application potential in motion assessment, health monitoring, and medical diagnosis. However, relying on a specialized instrument for power supply and signal reading makes sensors unsuitable for on-site detection. To solve this problem, a reusable self-powered electrochromic sensor patch based on enzymatic biofuel cells were constructed to realize the on-site visualized monitoring.
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January 2025
Beijing Spacecrafts Manufacturing Factory, Beijing 100094, P. R. China.
The rapid upsurge of metal-organic frameworks (MOFs) has sparked profound interest in their potential as proton conductors for proton exchange membrane fuel cells. However, proton-conducting behaviors of hydrophobic MOFs remain poorly understood compared with their hydrophilic counterparts, largely due to the absence of a microscopic phase separation structure akin to that found in Nafion membranes. Herein, we demonstrate a strategy for regulating the structures and proton conductivities of MOFs by separately incorporating hydrophobic -C(CF)- group alongside hydrophilic -O- and -SO- groups into organic ligands as linkers.
View Article and Find Full Text PDFChem Sci
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University Suzhou Jiangsu 215123 China
Understanding the oxygen reduction reaction (ORR) mechanism and accurately characterizing the reaction interface are essential for improving fuel cell efficiency. We developed an active learning framework combining machine learning force fields and enhanced sampling to explore the dynamics and kinetics of the ORR on Fe-N/C using a fully explicit solvent model. Different possible reaction paths have been explored and the O adsorption process is confirmed as the rate-determining step of the ORR at the Fe-N/C-water interface, which needs to overcome a free energy barrier of 0.
View Article and Find Full Text PDFScientificWorldJournal
January 2025
Department of Biochemistry and Biotechnology, College of Science, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana.
Bioethanol production is one of the key alternatives for fossil fuel use due to climate change. The study seeks to upscale tailor-made onsite enzyme blends for the bioconversion of cassava peels to bioethanol in simultaneous saccharification and fermentation (SSF) process using cassava peels-degrading fungi. The starch and cellulose contents of peels were determined.
View Article and Find Full Text PDFACS Biomater Sci Eng
January 2025
Environment Emission and CRM Section, CSIR-Central Institute of Mining and Fuel Research Dhanbad, Jharkhand, 828108, India.
Carbohydrate-functionalized quantum dots exhibit excellent physical characteristics and enhance the steric interaction with biological cells and tissues. Glycoconjugation of quantum dots promotes aqueous solubility, stability, and reduced immunogenicity. Carbohydrate-protein interactions are involved in various vital processes and provide insight into cellular recognition, cell-to-cell communication, pathogenicity, antigen-antibody recognition, and enzymatic action.
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