Light antiproton one-electron quasi-molecular ions within the relativistic A-DKB method.

J Chem Phys

Department of Physics, St. Petersburg State University, Petrodvorets, Oulianovskaya 1, 198504 St. Petersburg, Russia.

Published: December 2023

In the present work, two quasi-molecular compounds each involving one antiproton and one electron (p̄), He+-p̄ and H-p̄, are investigated. Using completely relativistic calculations within the finite-basis method adapted to systems with axial symmetry, the adiabatic potential curves are constructed by numerically solving the two-center Dirac equation. The binding energies of electron are obtained as a function of the inter-nuclear distance and compared with the corresponding nonrelativistic values and relativistic leading-order corrections calculated in the framework of other approaches. A semantic analysis of antiproton quasi-molecular ions with compounds containing a proton (p) instead of an antiproton is given. The advantages of the A-DKB method are demonstrated.

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http://dx.doi.org/10.1063/5.0181614DOI Listing

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