Using a conceptual framework based a) on a model where energy is the regulating agent and b) on the introduction of conjugated intensive and extensive quantities, together with the introduction from the beginning of the concepts of entropy and chemical potential allows to coherently model a variety of situations relating to didactically interesting examples referring to different disciplines.
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http://dx.doi.org/10.2533/chimia.2023.501 | DOI Listing |
Nano Lett
January 2025
Shenzhen Institute for Advanced Study, University of Electronic Science and Technology of China, Shenzhen 518110, China.
Efficient oxygen evolution reaction (OER) catalysts with fast kinetics, high efficiency, and stability are essential for scalable green production of hydrogen. The rational design and fabrication of catalysts play a decisive role in their catalytic behavior. This work presents a high-entropy catalyst, FeCoNiCuMo-O, synthesized via carbothermal shock.
View Article and Find Full Text PDFAdv Mater
January 2025
Frontiers Science Center for Flexible Electronics (FSCFE), MIIT Key Laboratory of Flexible Electronics (KLoFE), Northwestern Polytechnical University, Xi'an, 710072, China.
NaV(PO), based on multi-electron reactions between V/V/V, is a promising cathode material for SIBs. However, its practical application is hampered by the inferior conductivity, large barrier of V/V, and stepwise phase transition. Herein, these issues are addressed by constructing a medium-entropy material (NaVTiAlCrMnNi(PO), ME-NVP) with strong ME─O bond and highly occupied Na2 sites.
View Article and Find Full Text PDFSci Total Environ
January 2025
Inner Mongolia Key Laboratory of Advanced Ceramic Material and Devices, Baotou 014010, China.
Selective recovery of rare earth elements (REEs) from environmental waste is strategically significant. Herein, Ce(III) imprinted EDTA modified chitosan-magnetic graphene oxide (IIP-EDTA-CS-MGO) was prepared for selective recovery of Ce(III). Furthermore, adsorption mechanism was clarified based on versatile adsorption fittings and spectroscopic tests.
View Article and Find Full Text PDFSmall
January 2025
Institute for Sustainable Energy and Resources, Key Laboratory of Shandong Provincial Universities for Functional Molecules and Materials, College of Chemistry and Chemical Engineering, Qingdao University, Qingdao, Shandong, 266071, China.
Alkaline water (HO) electrolysis is currently a commercialized green hydrogen (H) production technology, yet the unsatisfactory hydrogen evolution reaction (HER) performance severely limits its energy conversion efficiency and cost reduction. Herein, PtRuFeCoNi high entropy alloys (HEAs) is synthesized and subsequently exploited electrochemically induced structural oxidation processes to construct self-reconfigurable HEAs, as an efficient alkaline HER catalyst. The optimized self-reconstructed PtRuFeCoNi HEAs with the HEAs and cobalt rutheniate interface (HEAs-CoRuO) exhibits excellent alkaline HER performance, requiring just 11.
View Article and Find Full Text PDFInt J Thermophys
January 2024
Material Measurement Laboratory, Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, CO 80305, USA.
The thermal conductivity of liquid -1,2-dichloroethene (R-1130(E)) was measured at temperatures ranging from 240 K to 340 K and pressures up to 25 MPa using a transient hot-wire instrument. A total of 447 thermal conductivity data points were measured along six isotherms. Each isotherm includes data at nine pressures, which were chosen to be at equal density increments starting at a pressure of 0.
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