Anaerobic removal of contaminants of emerging concern in municipal wastewater: Eco-toxicological risk evaluation and strategic selection of optimal treatment.

In the last decades, the interest for anaerobic process as a mainstream treatment of municipal wastewater increased due to the development of high-rate anaerobic bioreactors able to achieve removal kinetics comparable to the aerobic ones. Moreover, they have the additional advantages of energy production, nutrient recovery and reduced excess sludge yield, which are interesting features in the frame of sustainability wastewater treatment goals. These appealing factors increased the research demand to evaluate the potential of the anaerobic removal for contaminants of emerging concern (CECs) in municipal wastewater. However, despite the growing interest for the subject, literature is still fragmentary and reviews are mainly focused on specific technologies and target compounds or groups of compounds. We propose this review with the main objectives of presenting the state of knowledge, the performances of anaerobic systems for CECs' removal and, more important, to give the reader guidelines for optimal treatment selection. In the first part, a general overview of the investigated technologies at different scale, with a special focus on the recently proposed enhancements, is presented. Collected data are analysed to select the target CECs and the analysis results employed to define the optimal technological solution for their removal. A first novelty element of the paper is the original procedure for contaminant selection consisting of a risk assessment tool for CECs, based on their frequency of detection, concentration and potential for biosorption in wastewater treatment plants. Data of selected target CECs are combined with compound and technology performance data to implement a flowchart tool to evaluate the optimal treatment strategy, which constitute another, even more important, novelty element of this study.