We present an optical sensor based on light-induced thermoelastic spectroscopy for the detection of hydrogen sulfide (HS) in sulfur hexafluoride (SF). The sensor incorporates a compact multi-pass cell measuring 6 cm × 4 cm × 4 cm and utilizes a quartz tuning fork (QTF) photodetector. A 1.58 µm near-infrared distributed feedback (DFB) laser with an optical power of 30 mW serves as the excitation source. The sensor achieved a minimum detection limit (MDL) of ∼300 ppb at an integration time of 300 ms, corresponding to a normalized noise equivalent absorption coefficient (NNEA) of 3.96 × 10 W·cm·Hz. By extending the integration time to 100 s, the MDL can be reduced to ∼25 ppb. The sensor exhibits a response time of ∼1 min for a gas flow rate of 70 sccm.
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http://dx.doi.org/10.1016/j.pacs.2023.100553 | DOI Listing |
Sensors (Basel)
December 2024
National Key Laboratory of Laser Spatial Information, Harbin Institute of Technology, Harbin 150001, China.
In this paper, a highly sensitive methane (CH) sensor based on light-induced thermoelastic spectroscopy (LITES) and a T-shaped quartz tuning fork (QTF) with hydrogen (H) and helium (He) enhancement techniques are reported for the first time. The low resonant frequency self-designed T-shaped QTF was exploited for improving the energy accumulation time. H and He were utilized as surrounding gases for the T-shaped QTF to minimize energy loss, thereby enhancing the sensitivity of the LITES sensor.
View Article and Find Full Text PDFWe report a trace gas sensing technique of cavity-enhanced light-induced thermoelastic spectroscopy (CE-LITES) with a Fabry-Pérot (F-P) optical cavity and a high-quality-factor resonant quartz tuning fork (QTF). Pound-Drever-Hall (PDH) locking method is used to lock the laser to the optical cavity. With only a short 9-cm optical cavity (finesse, ∼1283) and a tiny commercially available standard QTF (Q-factor, ∼38910), a CE-LITES sensor for acetylene detection was developed to demonstrate this technique, achieving a minimum detection limit (MDL) of 7.
View Article and Find Full Text PDFAdv Sci (Weinh)
October 2024
Department of Nanoengineering, University of California San Diego, 9500 Gilman Drive, La Jolla, CA, 92093, USA.
Photoacoustics
August 2024
State Key Laboratory of Applied Optics, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China.
Quartz tuning fork (QTF)-based techniques of photoacoustic spectroscopy and thermoelastic spectroscopy play a significant role in trace gas sensing due to unique high sensitivity and compactness. However, the stability of both techniques remains plagued by the inevitable and unpredictable laser power variation and demodulation phase variation. Herein, we investigate the phase change of a QTF when integrating both techniques for enhanced gas sensing.
View Article and Find Full Text PDFAnal Chem
August 2024
Hefei Institute of Physical Science, Chinese Academy of Sciences, Hefei 230031, China.
Rapid and accurate realization of in situ analysis of deep-sea dissolved gases imperative to the study of ecological geology, oil and gas resource exploration, and global climate change. Herein, we report for the first time the deep-sea dissolved methane (CH) in situ sensor based on quartz-enhanced photoacoustic and light-induced thermoelastic spectroscopy. The developed sensor system has a volume of φ120 mm × 430 mm and a power consumption of 7.
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