The Ni-rich NCM622 is a promising cathode material for future high energy lithium ion batteries, but unstable electrochemical performance of NCM622 hinder its large scale commercial application. The cycling peformance of nickel-rich LiNiCoMnO (NCM622) cathode materials can be improved by surface coating. Here, a one-step approach based on TiF is used to successfully manufacture modified NCM622 cathode materials with a TiO-LiF coating. The TiO-LiF coated NCM622 preserves 79.7% capacity retention which is higher than the pure NCM622 (68.9%) at 1C after 200 cycles within 2.7-4.3 V. This material serves as the cathode for lithium-ion batteries (LIBs). The uniform TiO-LiF coating layer can alleviate structural degradation brought on by unfavorable side reactions with the electrolyte has been validated. TiO-LiF coated on NCM622 cathode materials can be modified easily by one-step approach.
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http://dx.doi.org/10.1039/d3ra05659g | DOI Listing |
Nanomaterials (Basel)
December 2024
Department of Chemical, Biological and Battery Engineering, Gachon University, Seongnam-si 13120, Gyeonggi-do, Republic of Korea.
To develop an advanced anode for lithium-ion batteries, the electrochemical performance of a novel material comprising a porous artificial carbon (PAC)-Si composite was investigated. To increase the pore size and surface area of the composite, ammonium bicarbonate (ABC) was introduced during high-energy ball-milling, ensuring a uniform distribution of silicon within the PAC matrix. The physical and structural properties of the developed material were evaluated using several advanced techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), and galvanostatic intermittent titration (GITT).
View Article and Find Full Text PDFJ Colloid Interface Sci
November 2024
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, Qinhuangdao 066004, Hebei, China; School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, Hebei, China. Electronic address:
Rare earth elements, characterized by their high-energy d-shell and f-shell electrons, large charge density, and substantial atomic radius, theoretically offer enhanced electronic states near the Fermi level. Doping rare earth elements into electrode materials can improve the internal electronic conductivity of the material. However, there are relatively few studies and reports on the mechanisms of rare earth elements in optimizing LiNiCoMnO (NCM) materials.
View Article and Find Full Text PDFEnviron Sci Technol
October 2024
Department of Battery and Chemical Engineering, Changwon National University, Changwon, Gyeongsangnam-do 51140, Republic of Korea.
J Colloid Interface Sci
January 2025
College of Chemistry and Environmental Engineering, International Joint Research Center for Molecular Science, Shenzhen University, Shenzhen, Guangdong 518060, PR China. Electronic address:
Plastic-crystal-embedded elastomer electrolytes (PCEEs), produced through polymerization-induced phase separation (PIPS), are gaining popularity as solid polymer electrolytes (SPEs). However, it remains to be investigated whether all monomer molecules can achieve polymerization-induced phase separation and the corresponding differences in lithium metal battery performance. Herein, we prepared PCEEs with different functional groups (OH, CN, F) through in situ polymerization.
View Article and Find Full Text PDFNanomicro Lett
June 2024
School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, People's Republic of China.
Nickel-rich layered oxide LiNiCoMnO (NCM, x + y + z = 1) is the most promising cathode material for high-energy lithium-ion batteries. However, conventional synthesis methods are limited by the slow heating rate, sluggish reaction dynamics, high energy consumption, and long reaction time. To overcome these challenges, we first employed a high-temperature shock (HTS) strategy for fast synthesis of the NCM, and the approaching ultimate reaction rate of solid phase transition is deeply investigated for the first time.
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