We propose a concept for generation of ultrashort pulses based on transient field-induced plasmonic resonance in nanoparticle composites. Photoionization and free-carrier plasma generation change the susceptibility of nanoparticles on a few-femtosecond scale under the action of the pump pulse. This opens a narrow time window when the system is in plasmonic resonance, which is accompanied by a short burst of the local field. During this process, frequency-tunable few-fs pulses can be emitted. This paves a way to ultra-compact yet efficient generation of ultrashort pulses at short wavelengths.
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http://dx.doi.org/10.1364/OE.501153 | DOI Listing |
Chem Sci
January 2025
Department of Chemistry, Rice University Houston Texas 77005 USA
We recently demonstrated molecular plasmons in cyanine dyes for the conversion of photon energy into mechanical energy through a whole-molecule coherent vibronic-driven-action. Here we present a model, a molecular plasmon analogue of molecular orbital theory and of plasmon hybridization in metal nanostructures. This model describes that molecular plasmons can be obtained from the combination or hybridization of elementary molecular fragments, resulting in molecules with hybridized plasmon resonances in the electromagnetic spectrum.
View Article and Find Full Text PDFNanoscale Adv
January 2025
School of Electrical Engineering and Computer Science, University of Ottawa Ottawa Ontario K1N 6N5 Canada
Interference of surface plasmons has been widely utilized in optical metrology for applications such as high-precision sensing. In this paper, we introduce a surface plasmon interferometer with the potential to be arranged in arrays for parallel multiplexing applications. The interferometer features two grating couplers that excite surface plasmon polariton (SPP) waves traveling along a gold-air interface before converging at a gold nanoslit where they interfere.
View Article and Find Full Text PDFJ Ethnopharmacol
January 2025
The Affiliated Guangdong Second Provincial General Hospital of Jinan University, Guangzhou, Guangdong, China. Electronic address:
Ethnopharmacological Relevance: The rhizome of Curcuma phaeocaulis Valeton, Curcuma wenyujin Y.H. Chen & C.
View Article and Find Full Text PDFTalanta
January 2025
Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95122, Catania, Italy; INBB, Istituto Nazionale di Biostrutture e Biosistemi, Viale delle Medaglie d'Oro, 305, 00136, Roma, Italy. Electronic address:
Directly detecting biomarkers in liquid biopsy for diagnosis and personalized treatment plays a crucial role in managing cancer relapse and increasing survival rates. Typically, the standard analysis of circulating tumour DNA requires lengthy isolation, extraction, and amplification steps, leading to sample contamination, longer turnaround time and higher assay costs. Surface plasmon resonance is an emerging and promising technology for rapid and real-time dynamic biomarker monitoring in liquid biopsy.
View Article and Find Full Text PDFChem Asian J
January 2025
Universidad Austral de Chile, Instituto de Ciencias Químicas, CHILE.
Plasmonic materials can be utilized as effective platforms to enhance luminescent signals of luminescent metal nanoclusters (LMNCs). Both surface enhanced fluorescence (SEF) and shell-isolated nanoparticle-enhanced fluorescence (SHINEF) strategies take advantage of the localized and increased external electric field created around the plasmonic metal surface when excited at or near their characteristic plasmonic resonance. In this context, we present an experimental and computational study of different plasmonic composites, (Ag) Ag@SiO2 and (Au) Au@SiO2 nanoparticles, which were used to enhance the luminescent signal of Au nanoclusters coated with glutathione (GSH) molecule (Au25GSH NCs).
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