The silsesquioxane ligand (Bu)SiO(OH) (POSSH) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U(POSS)]) that exhibits magnetic communication and promotes dinitrogen reduction in the presence of reducing agent.
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| http://dx.doi.org/10.1039/d3cc05390c | DOI Listing |
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