Perylene diimide-based radical anions for the rapid detection of picomolar HO in an aqueous medium.

Chem Commun (Camb)

Department of Chemistry, UGC Centre for Advanced Studies-II, Guru Nanak Dev University, Amritsar 143001, Punjab, India.

Published: December 2023

The formation of radical anions (PDI 1˙) using HS as a sacrificial electron donor in 50% HEPES buffer-THF solution is reported. PDI 1˙ was confirmed by optical, - plot, CV, DPV, NOBF and EPR studies. PDI 1˙ has a half-life of 96 minutes in solution and 11 days in the solid state without any additive. The formation of PDI 1˙ was confirmed by AFM and SEM. PDI 1˙ can be used for the detection of 26.6 pM of HO supported by optical and CV data.

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http://dx.doi.org/10.1039/d3cc03690aDOI Listing

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