Pushing the Detection Limit of Static Wideline NMR Spectroscopy Using Ultrafast Frequency-Swept Pulses.

J Phys Chem Lett

Institute for Physical Chemistry, University of Münster, Corrensstrasse 28/30, DE-48149 Münster, Germany.

Published: December 2023

We report a simple design strategy for wideband uniform-rate smooth truncation (WURST) pulses that enables ultrafast frequency sweeps to maximize the sensitivity of Carr-Purcell-Meiboom-Gill (CPMG) acquisition in static wideline nuclear magnetic resonance (NMR). Three compelling examples showcase the advantage of ultrafast frequency sweeps over currently employed WURST-CPMG protocols, demonstrating the potential of investigating materials that are typically inaccessible to static wideline NMR techniques, e.g., paramagnetic solids with short homogeneous transverse relaxation times.

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http://dx.doi.org/10.1021/acs.jpclett.3c02758DOI Listing

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