Chitosan is a widely available polymer with a reasonably high abundance, as well as a sustainable, biodegradable, and biocompatible material with different functional groups that are used in a wide range of operations. Chitosan is frequently employed in widespread applications such as environmental remediation, adsorption, catalysts, and drug formulation. The goal of this review is to discuss the potential applications of chitosan and its chemically modified solids as a catalyst in biodiesel production. The existing manuscripts are integrated based on the nature of materials used as chitosan and its modifications. A short overview of chitosan's structural characteristics, properties, and some ideal methods to be considered in catalysis activities are addressed. This article includes an analysis of a chitosan-based scientometric conducted between 1975 and 2023 using VOS viewer 1.6.19. To identify developments and technological advances in chitosan research, the significant scientometric features of yearly publication results, documents country network, co-authorship network, documents funding sponsor, documents institution network, and documents category in domain analysis were examined. This review covers a variety of organic transformations and their effects, including chitosan reactions against acids, bases, metals, metal oxides, organic compounds, lipases, and Knoevenagel condensation. The catalytic capabilities of chitosan and its modified structures for producing biodiesel through transesterification reactions are explored in depth.
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http://dx.doi.org/10.1016/j.carbpol.2023.121567 | DOI Listing |
Sci Rep
January 2025
Process and Energy Department, University of Technology of Delft, Leeghwaterstraat 39, 2628 CB, Delft, The Netherlands.
An urgent ecological issue is the threat posed by invasive species, which are becoming more widespread especially in Africa. These encroachments damage ecosystems, pose a threat to biodiversity, and outcompete local plants and animals. This article focuses on converting Acacia Mellifera from Namibia, commonly known as encroacher bush (EB) into high-quality drop-in intermediates for the chemical and transport industry via hydrothermal liquefaction (HTL).
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January 2025
Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bharu, Malaysia.
As the demand for sustainable energy sources intensifies, biodiesel emerges as a compelling renewable alternative to petroleum-based fuels. Leveraging waste cooking oil (WCO) as a feedstock not only offers an environmentally friendly fuel source but also addresses waste disposal issues. However, biodiesel production from WCO faces challenges, particularly due to its high free fatty acid (FFA) content, which can hinder efficient conversion and lead to soap formation in traditional alkaline-catalysed processes.
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December 2024
Department of Mechanical and Mechatronics Engineering, Faculty of Engineering, Prince of Songkla University, Hat Yai, Songkhla 90110, Thailand.
In this study, high-intensity ultrasound (1000 W ultrasonic power and 18 kHz frequency) was employed in conjunction with heterogeneous acid catalysts to reduce the free fatty acid (FFA) content in palm fatty acid distillate (PFAD). The aim was to convert the FFAs in PFAD to methyl esters (MEs) through an esterification process. The use of Amberlyst-15 as a heterogeneous acid catalyst offers environmental advantages over homogeneous catalysts and the potential for reuse in the biodiesel production process.
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December 2024
Plant Ecology and Environmental Botany Unit, Department of Plant Biology, University of Ilorin, Ilorin, Nigeria.
The conversion of agricultural wastes to value-added products has emerged as a pivotal strategy in fostering economic transformation. This chapter explores the transformative potential of converting agricultural residues into valued commodities that contribute to sustainability and economic growth. Agricultural wastes, often considered environmental liabilities, possess untapped benefits with great economic value.
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December 2024
Center of Excellence in Catalysis and Catalytic Reaction Engineering, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, 10330, Thailand.
Glycerol, a by-product of biodiesel production, could be converted into various value-added products. This work focuses on its dehydrogenation to dihydroxyacetone (DHA), which is mainly used in the cosmetics industry. While several methods have been employed for DHA production, some necessitate catalysts and involve harsh reaction conditions as well as long reaction times.
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