A simple and highly effective methodology for the cross-coupling of heteroaryl iodides with NN-AuPPh at room temperature is reported. The protocol is based on a novel catalytic system consisting of Pd(dba)·CHCl and the phosphine ligand CgPPh having an adamantane-like framework. The present protocol was found to be well compatible with various heteroaryl iodides, thus opening new horizons in directed synthesis of functionalized nitronyl nitroxides and high-spin molecules.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10675334 | PMC |
| http://dx.doi.org/10.3390/molecules28227661 | DOI Listing |
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