Lithium-ion batteries (LIBs) have recently become popular for energy storage due to their high energy density, storage capacity, and long-term cycle life. Although binders make up only a small proportion of LIBs, they have become the key to promoting the transformation of the battery preparation process. Along with the development of binders, the battery manufacturing process has evolved from the conventional slurry-casting (SC) process to a more attractive solvent-free (SF) method. Compared with traditional LIBs manufacturing method, the SF method could dramatically reduce and increase the energy density due to the reduced preparation steps and enhanced electrode loading. Polytetrafluoroethylene (PTFE), as a typical binder, has played an important role in fabricating high-performance LIBs, particularly in regards to the SF technique. In this paper, the development history and application status of PTFE binder was introduced, and then its contributions and the inherent problems involved in the SF process were described and analyzed. Finally, the viewpoints concerning the future trends for PTFE-based SF manufacturing methods were also discussed. We hope this work can inspire future research concerning high-quality SF binders and assist in promoting the evolution of the SF manufacturing technology in regards to LIBs.
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http://dx.doi.org/10.3390/ma16227232 | DOI Listing |
Langmuir
January 2025
College of Chemistry and Chemical Engineering, Qingdao University, Qingdao 266071, China.
The recovery of valuable materials from spent lithium-ion batteries (LIBs) has experienced increasing demand in recent years. Current recycling technologies are typically energy-intensive and are often plagued by high operation costs, low processing efficiency, and environmental pollution concerns. In this study, an efficient and environmentally friendly dielectrophoresis (DEP)-based approach is proposed to separate the main components of "black mass" mixtures from LIBs, specifically lithium iron phosphate (LFP) and graphite, based on their polarizability differences.
View Article and Find Full Text PDFSmall
January 2025
National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology, Key Laboratory of Advanced Battery Materials of Yunnan Province, Faculty of Metallurgical and Energy Engineering, Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, China.
Owing to its abundant manganese source, high operating voltage, and good ionic diffusivity attributed to its 3D Li-ion diffusion channels. Spinel LiMnO is considered a promising low-cost positive electrode material in the context of reducing scarce elements such as cobalt and nickel from advanced lithium-ion batteries. However, the rapid capacity degradation and inadequate rate capabilities induced by the Jahn-Teller distortion and the manganese dissolution have limited the large-scale adoption of spinel LiMnO for decades.
View Article and Find Full Text PDFDalton Trans
January 2025
School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510640, P. R. China.
CaCoO/rGO was prepared by combining a sol-gel strategy and mechanical ball milling method. The Rietveld refinement results demonstrated a single-phase structure with a monoclinic symmetry. When utilized as an anode for lithium-ion batteries, it exhibited excellent rate performance and electrochemical stability due to the significantly decreasing particle size as well as the formation of a conductive rGO network in the composite after ball milling.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Chemical Engineering and Materials Science, and Graduate Program in System Health Science and Engineering, Ewha Womans University, Seoul 03760, Republic of Korea.
Spinel lithium manganese oxide (LiMnO, LMO) is a promising cathode material with nontoxicity, high operating voltage, and low cost. However, structural collapse during battery cycling ─ caused by Mn dissolution and the Jahn-Teller effect ─ is a critical disadvantage, reducing cycle retention, particularly at high temperatures. In this study, to solve these critical issues, we introduce Cu(HITP) (CuHITP; HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a conductive two-dimensional (2D) metal-organic framework (MOF) as a surface coating material.
View Article and Find Full Text PDFAdv Mater
January 2025
School of Materials Science and Engineering, Beihang University, Beijing, 100191, China.
Amid the burgeoning demand for electrochemical energy storage and neuromorphic computing, fast ion transport behavior has attracted widespread attention at both fundamental and practical levels. Here, based on the nanoconfined channel of graphene oxide laminar membranes (GOLMs), the lithium ionic conductivity typically exceeding 10 mS cm is realized, one to three orders of magnitude higher than traditional liquid or solid lithium-ion electrolyte. Specifically, the nanoconfined lithium hexafluorophosphate (LiPF)-ethylene carbonate (EC)/ dimethyl carbonate (DMC) electrolyte demonstrates the ionic conductivity of 170 mS cm, outperforming the bulk counterpart by ≈16 fold.
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