The research presented in this article was conducted to evaluate the suitability of recycled foam concrete (RFC) as an ingredient in newly created cement mortars. The basis for an analysis was the assumption that the waste is collected selectively after separation from other waste generated during demolition. The motivation for the research and its main problem is a comparison of the performance of RFC used in various forms. RFC was used in two forms: (1) recycled foam concrete dust (RFCD) as a 25 and 50% replacement of cement, and (2) recycled foam concrete fine aggregate (RFCA) as a 10, 20, and 30% replacement of sand. The basic properties of fresh and hardened mortars were determined: consistency, density, initial setting time, absorbability, compressive strength, thermal conductivity coefficient, and heat capacity. Research is complemented with SEM observations. The properties of fresh mortars and mechanical parameters were decreased with the usage of any dosage of RFC in any form, but the thermal properties were improved. The required superplasticizer amount for proper consistency was raised four times for replacing cement with 50% of RFCD than for 25% of such replacement. The mix density dropped by about 8% and 9% for mortars with the replacement of 50% cement by RFCD and 30% sand by RFCA in comparison to reference mortar. A 30% decrease in initial setting time was observed for cement replacement. In the case of sand replacement, it was the opposite-an increase of 100%. The dry density decreased by about 14% and 11% for mortars with the replacement of 50% cement by RFCD and 30% sand by RFCA in comparison to reference mortar. Absorbability was raised by about two times after replacement with both RFCD and RFCA. Compressive strength after 28 days dropped significantly by 75% and 60%, and the thermal conductivity coefficient decreased by 20% and 50% with 50% RFCD added instead of cement and 30% RFCA replacing sand. It indicates greater efficiency in thermomechanical means from RFCA in comparison to RFCD. This material can be used especially in the production of plaster and masonry mortar. Linear correlations of dry density and thermal conductivity coefficient and the latter and compressive strength were proven as reliable for RFCD replacement of cement and RFCA replacement of sand in mortars with greater w/c ratio.
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http://dx.doi.org/10.3390/ma16227169 | DOI Listing |
ACS Nano
January 2025
Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, United States.
Biogenic-based foam, renowned for its sustainable and eco-friendly properties, is emerging as a promising thermal insulating material with the potential to significantly enhance energy efficiency and sustainability in building applications. However, its relatively high thermal conductivity, large-pore configurations, and energy-intensive manufacturing processes hinder its widespread use. Here, we report on the scalable, one-pot synthesis of biogenic foams achieved by integrating recycled paper pulp and in situ nanoporous silica formation, resulting in a hierarchical structure comprising both micropores and nanopores.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
Cellulose-based porous materials are promising for various fields and preferred for sustainable development. However, the low mechanical properties and high hydrophilicity of cellulose-based xerogels had a direct influence on their application in oil absorption. To address the challenge, an environmentally friendly and economical method for synthesizing MTMS/C0.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
I2M (Institut de Mécanique et d'Ingénierie), UMR 5295, CNRS, University of Bordeaux, 33400 Talence, France.
From both economic and environmental points of view, the reuse of dredged sediments in the direct onsite casting of concrete represents a promising method for replacing sand. The aim of this study was to develop a cementitious material that (i) reuses the thin particles of sediments; (ii) has a low density due to the incorporation of air foam in the material; and (iii) achieves a minimum mechanical strength of 0.5 MPa for embankment applications.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, Poland.
The aim of this work was to synthesize polyurethane foams based on petrochemical polyols and biopolyols with specific apparent densities (40, 60, 80, 100, and 120 kg/m), test their properties, glycolyze them, and finally analyze each glycolyzed product. The petroleum-based foams, used as reference foams, and the bio-based foams underwent a series of standard tests to define their properties (the content of closed cells 20-95%, compressive strength 73-1323 kPa, thermal conductivity 24-42 mW/m∙K, brittleness 4.6-82.
View Article and Find Full Text PDFChem Sci
December 2024
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University Changchun Jilin 130012 China
The chemical recycling of polystyrene (PS) waste to value-added aromatic compounds is an attractive but formidable challenge due to the inertness of the C-C bonds in the polymer backbone. Here we develop a light-driven, copper-catalyzed protocol to achieve aerobic oxidation of various alkylarenes or real-life PS waste to benzoic acid and oxidized styrene oligomers. The resulting oligomers can be further transformed under heating conditions, thus achieving benzoic acid in up to 65% total yield through an integrated one-pot two-step procedure.
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