In order to solve the problem of external corrosion of deep well casing in oil and gas fields, a new type of high-temperature-resistant zinc alloy sacrificial anode material was used. The temperature and corrosion resistance of the new anode material and TP140 casing were investigated by simulating the high-temperature working conditions of a deep well in an oil field using high-temperature and high-pressure corrosion tests and electrochemical tests. The results showed that at 100-120 °C, the corrosion rate of TP140 protected by a sacrificial anode was only one-tenth of that under unprotected conditions, and the minimum corrosion rate of TP140 protected by a sacrificial anode at 100 °C was 0.0089 mm/a. The results of the dynamic potential polarization curve showed that the corresponding corrosion current density of TP140 first increased and then decreased with the increase in temperature. The self-corrosion potential in sacrificial anode materials first increased and then decreased with the increase in temperature, and the potential difference with TP140 gradually decreased.
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http://dx.doi.org/10.3390/ma16227120 | DOI Listing |
Chem Commun (Camb)
January 2025
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, 510640 Guangzhou, P. R. China.
Herein, we report a novel electrochemical hydrogenolysis method for β-O-4 bond cleavage by using carbon foam as the cathode and waste aluminum as the anode. The reaction takes place at the cathode, producing ketones and phenolic compounds. Employing waste aluminum as the anode could avoid anodic excessive oxidation of phenols.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemical Engineering and Conn Center for Renewable Energy ResearchUniversity of Louisville, 132 Eastern Parkway, Louisville, Kentucky 40292, United States.
We report a silicon anode for lithium-ion batteries consisting of a layer of 100% nanotubes directly bonded to copper foil. The process involved silicon deposition on a sacrificial zinc oxide nanorod film and removal of zinc oxide to produce a nanotube film directly on thin copper foils. The thickness of resulting films ranged from 9 to 20 μm with Si nanotubes having diameters of 200-400 nm and lengths of 2-10 μm.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Key Laboratory of Green and High-end Utilization of Salt Lake Resources, Qinghai Provincial Key Laboratory of Resources and Chemistry of Salt Lakes, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, Qinghai 810008, China. Electronic address:
The yolk-shell architecture offers a promising solution to the challenges of silicon (Si) anodes in lithium-ion batteries (LIBs), particularly in addressing the significant volume changes that occur during charge and discharge cycles. However, traditional construction methods often rely on sacrificial templates and acid or alkali etching, which limits industrial applicability. In this work, we successfully constructed a silicon/carbon (Si/C) composite with a multicore yolk-shell structure using scalable spray drying technology and in-situ growth of metal-organic frameworks (MOFs) at room temperature.
View Article and Find Full Text PDFHeliyon
January 2025
Materials and Process Simulation Center, California Institute of Technology, Pasadena, CA, 91125, USA.
Electrochemical energy storage plays a critical role in the transition to clean energy. With the growing demand for efficient and sustainable energy solutions, supercapacitors have gained significant attention due to their high specific capacitance, rapid charge/discharge capabilities, long lifespan, safe operation across various temperatures, and minimal maintenance needs. This study introduces a novel approach for the synthesis of high-performance supercapacitor electrodes by using MnNi-MOF-74 as a precursor.
View Article and Find Full Text PDFACS Nano
January 2025
School of Physics and Astronomy, Monash University, Clayton, Victoria 3800, Australia.
Van der Waals electrode integration is a promising strategy to create nearly perfect interfaces between metals and 2D materials, with advantages such as eliminating Fermi-level pinning and reducing contact resistance. However, the lack of a simple, generalizable pick-and-place transfer technology has greatly hampered the wide use of this technique. We demonstrate the pick-and-place transfer of prefabricated electrodes from reusable polished hydrogenated diamond substrates without the use of any sacrificial layers due to the inherent low-energy and dangling-bond-free nature of the hydrogenated diamond surface.
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